SYNTHESIS OF NEW VINYLSILANES CONTAINING AN ASYMMETRIC SILICON VIA PLATINUM CATALYZED HYDROSILYLATION OF ACETYLENE AND MONOSUBSTITUTED ALKYNES

被引：13

作者：

GEVORGYAN, V ^{[1
]}

BORISOVA, L ^{[1
]}

POPELIS, J ^{[1
]}

LUKEVICS, E ^{[1
]}

FOLTYNOWICZ, Z ^{[1
]}

GULINSKI, J ^{[1
]}

MARCINIEC, B ^{[1
]}

机构：

[1] ADAM MICKIEWICZ UNIV,FAC CHEM,PL-60780 POZNAN,POLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 424卷 / 01期

关键词：

D O I：

10.1016/0022-328X(92)85002-E

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of new racemic vinylsilanes has been obtained by hydrosilylation reaction of acetylene and monosubstituted alkynes with (+/-)-alpha-NpPhMeSiH and (+/-)-N(CH2CH2O)3SiCH2PhMeSiH in the presence of platinum-containing catalysts.

引用

页码：15 / 22

页数：8

共 15 条

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[13] STEREOCHEMISTRY OF ASYMMETRIC SILICON . STEREOSPECIFIC PLATINUM-CATALYZED HYDROSILATION OF 1-OCTENE WITH OPTICALLY ACTIVE R3SI]H
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (06) : 1519 - &
[14] STEREOCHEMISTRY OF ASYMMETRIC SILICON .I. RELATIVE + ABSOLUTE CONFIGURATIONS OF OPTICALLY ACTIVE ALPHA-NAPHTHYLPHENYLMETHYLSILANES
SOMMER, LH
MICHAEL, KW
FRYE, CL
PARKER, GA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (16) : 3271 - &
[15] ZAPPEL A, 1958, Patent No. 2839557

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