DETERMINATION OF SELF-ACCELERATING DECOMPOSITION TEMPERATURES USING THE ACCELERATING RATE CALORIMETER

被引：69

作者：

FISHER, HG

GOETZ, DD

机构：

[1] Central Research and Engineering Technology, Union Carbide Chemicals and Plastics Company, Inc., South Charleston, WV 25303

来源：

JOURNAL OF LOSS PREVENTION IN THE PROCESS INDUSTRIES | 1991年 / 4卷 / 05期

关键词：

DECOMPOSITION; CALORIMETRY; SELF-ACCELERATING DECOMPOSITION TEMPERATURE;

D O I：

10.1016/0950-4230(91)80044-U

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A self-accelerating decomposition temperature (T(SADT)) is the minimum ambient air temperature at which a reactive material of specified stability decomposes in a specified commercial package in a period of 7 days or less. Values for T(SADT) are determined to decide whether a substance should be subject to temperature control during transport. Values of T(SADT) calculated using the Accelerating Rate Calorimeter (ARC) and techniques suggested by Wilberforce and the authors are compared to those measured by oven stability testing. The methodology and the advantages of using the ARC to obtain T(SADT) values are discussed.

引用

页码：305 / 316

页数：12

共 12 条

[1]

Wilberforce, The use of the Accelerating Rate Calorimeter to Determine the SADT of Organic Peroxides, Internal Report, (1981)

[2]

Recommendations on the Transport of Dangerous Goods, pp. 263-275, (1989)

[3]

Recommendations on the Transport of Dangerous Goods, Tests and Criterion, pp. 168-189, (1986)

[4]

The ARC Formula for the Chemical Processing Industries, (1980)

[5]

Townsend, Tou, Thermochim. Acta, 37, (1980)

[6]

Kern, Process Heat Transfer, (1950)

[7]

Accelerating Rate Calorimeter Operating Manual, (1981)

[8]

Leung, Fauske, Fisher, Thermochim. Acta, 104, (1986)

[9]

Wilberforce, Inst. Chem. Eng. Symp. Ser. No. 85, (1984)

[10]

Cronin, Nolan, Plant Oper. Prog., 6, 2, (1987)

← 1 2 →