AN EFFICIENT HETEROGENIZED PALLADIUM CATALYTIC-SYSTEM FOR THE REDUCTIVE CARBONYLATION OF NITROBENZENE TO METHYL-N-PHENYLCARBAMATE

被引：8

作者：

CHOUDARY, BM ^{[1
]}

RAO, KK ^{[1
]}

PIROZHKOV, SD ^{[1
]}

LAPIDUS, AL ^{[1
]}

机构：

[1] ND ZELINSKII INST ORGAN CHEM,MOSCOW,RUSSIA

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 88卷 / 01期

关键词：

CARBONYLATION; METHYL-N-PHENYLCARBAMATE; MONTMORILLONITE; PALLADIUM; PYRIDINE; REDUCTION;

D O I：

10.1016/0304-5102(93)E0250-K

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A highly active and selective heterogenised homogeneous catalyst, montmorillonitebipyridinepalladium (II) acetate complex for the reductive carbonylation of nitrobenzene to methyl N-phenylcarbamate is reported. With the additional advantages such as ease of filterability and reusability for several cycles with consistent activity and selectivity, the heterogenised system will become practical alternative to the other systems described earlier.

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页码：23 / 30

页数：8

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