AN EFFICIENT HETEROGENIZED PALLADIUM CATALYTIC-SYSTEM FOR THE REDUCTIVE CARBONYLATION OF NITROBENZENE TO METHYL-N-PHENYLCARBAMATE

被引：8

作者：

CHOUDARY, BM ^{[1
]}

RAO, KK ^{[1
]}

PIROZHKOV, SD ^{[1
]}

LAPIDUS, AL ^{[1
]}

机构：

[1] ND ZELINSKII INST ORGAN CHEM,MOSCOW,RUSSIA

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 88卷 / 01期

关键词：

CARBONYLATION; METHYL-N-PHENYLCARBAMATE; MONTMORILLONITE; PALLADIUM; PYRIDINE; REDUCTION;

D O I：

10.1016/0304-5102(93)E0250-K

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A highly active and selective heterogenised homogeneous catalyst, montmorillonitebipyridinepalladium (II) acetate complex for the reductive carbonylation of nitrobenzene to methyl N-phenylcarbamate is reported. With the additional advantages such as ease of filterability and reusability for several cycles with consistent activity and selectivity, the heterogenised system will become practical alternative to the other systems described earlier.

引用

页码：23 / 30

页数：8

共 9 条

[1] Palladium and silver reductive catalyzed carbonylation of nitrobenzene to methyl N-phenylcarbamate
Santi, R
Romano, AM
Panella, F
Santini, C
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 127 (1-3) : 95 - 99
[2] The carbonylation reaction of nitrobenzene to methyl phenylcarbamate: Highly efficient promoters for the palladium-phenanthroline catalytic system based on phosphorus acids
Ragaini, F
Cognolato, C
Gasperini, M
Cenini, S
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (25) : 2886 - 2889
[3] Phosphorus acids as highly efficient promoters for the palladium-phenanthroline catalyzed carbonylation of nitrobenzene to methyl phenylcarbamate
Ragaini, F
Gasperini, M
Cenini, S
ADVANCED SYNTHESIS & CATALYSIS, 2004, 346 (01) : 63 - 71
[4] Carbonylation of nitrobenzene to N-methyl phenylcarbamate catalyzed by palladium-phenanthroline complexes -: Bifunctional activation by anthranilic acid
Gasperini, M
Ragaini, F
Cenini, S
Gallo, E
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 204 : 107 - 114
[5] Nitrogen ligands effects in the palladium-catalyzed carbonylation reaction of nitrobenzene to give N-methyl phenylcarbamate
Ferretti, Francesco
Gallo, Emma
Ragaini, Fabio
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2014, 771 : 59 - 67
[6] Mineral Oil/Methanol: A Cheap Biphasic Reaction Medium with Thermomorphic Properties and Its Application to the Palladium-Catalyzed Carbonylation of Nitrobenzene to Methyl Phenylcarbamate
Ferretti, Francesco
Gallo, Emma
Ragaini, Fabio
CHEMCATCHEM, 2015, 7 (14) : 2241 - 2247
[7] A New Pd-Based Catalytic System for the Reductive Carbonylation of Nitrobenzene to Form N-(4-hydroxyphenyl)acetamide Selectively in One Pot
Vavasori, Andrea
Capponi, Marco
Ronchin, Lucio
REACTIONS, 2023, 4 (04): : 725 - 736
[8] Palladium on Carbon: An Efficient, Heterogeneous and Reusable Catalytic System for Carbonylative Synthesis of N-Substituted Phthalimides
Khedkar, Mayur V.
Khan, Shoeb R.
Sawant, Dinesh N.
Bagal, Dattatraya B.
Bhanage, Bhalchandra M.
ADVANCED SYNTHESIS & CATALYSIS, 2011, 353 (18) : 3415 - 3422
[9] Synthesis of 2-methyl-4-methoxydiphenylamine by palladium catalyzed C-N coupling-high synthetic versatility by use of a flexible catalytic system
Scholz, U
Schlummer, B
TETRAHEDRON, 2005, 61 (26) : 6379 - 6385

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