ASYMMETRICAL SYNTHESIS OF ORGANOMETALLIC ANALOGS OF NATURAL COMPOUNDS .8. REACTIONS OF PENTAFLUOROBENZALDEHYDE WITH THE NI(II) COMPLEX OF A SCHIFF-BASE OF GLYCINE AND (S)-2-[N-(BENZYLPROLYL)AMINO]BENZOPHENONE

被引：1

作者：

SOLOSHONOK, VA ^{[1
]}

SVISTUNOVA, NY ^{[1
]}

KUKHAR, VP ^{[1
]}

KUZMINA, NA ^{[1
]}

BELOKON, YN ^{[1
]}

机构：

[1] UKRAINIAN ACAD SCI,BIOORGAN CHEM & PETR CHEM INST,252028 KIEV,UKRAINE,USSR

来源：

BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE | 1992年 / 41卷 / 03期

关键词：

ASYMMETRICAL SYNTHESIS; PENTAFLUOROBENZALDEHYDE; SCHIFF BASE; FLUORINE-SUBSTITUTED BETA-PHENYLSERINES;

D O I：

10.1007/BF00863081

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of pentafluorobenzaldehyde with a Ni(II) complex of a Schiff base formed from glycine and (S)-2-[N-(benzylprolyl)amino]benzophenone yields, depending on the reaction conditions, the hitherto unknown, disastereo and enantiomerically pure amino acids 2R,3S-beta-(4-methoxytetrafluorophenyl)serine, 2S,3R-beta-(4-methoxytetrafluorophenyl) serine, 2S,3S-beta-(pentafluorophenyl)serine, and 2S,3R-beta-(pentafluorophenyl)serine.

引用

页码：540 / 545

页数：6

共 2 条

[1] Asymmetric Synthesis of L-[β-11C]-3,4-Dihydroxyphenylalanine via the Chiral Ni(II) Complex of the Schiff Base Derived from (S)-o-N-(N'-Benzylprolyl)aminobenzophenone and Glycine (Ni-BPB-Gly)
O. F. Kuznetsova
I. K. Mosevich
M. V. Korsakov
O. S. Fedorova
R. N. Krasikova
Radiochemistry, 2002, 44 (6) : 582 - 587
[2] Long-range J(15N,13C) and J(13C,13C) coupling constants via the metal atom in 13C NMR spectra of square-planar Ni(II) complexes of the Schiff base of (S)-2-(N-benzylprolyl)aminobenzophenone and 13C-1-, 13C-2- or 15N-labelled glycine
Jirman, J
Nádvornik, M
Sopková, J
Popkov, A
MAGNETIC RESONANCE IN CHEMISTRY, 1998, 36 (05) : 351 - 355

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