A SURFACE ENHANCED RAMAN-SPECTROSCOPY STUDY OF THE CORROSION-INHIBITING PROPERTIES OF BENZIMIDAZOLE AND BENZOTRIAZOLE ON COPPER

被引:63
作者
CARRON, KT
GI, X
LEWIS, ML
机构
[1] Department of Chemistry, University of Wyoming, Laramie
关键词
D O I
10.1021/la00049a001
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Surface enhanced Raman spectra of benzimidasole and benzotriazole on copper have been obtained. A characteristic imidazole ring stretching mode located near 780 cm-1 shows a splitting in the benzotriazole-copper surface complex. This splitting is not observed in benzimidazole. The spectrum of benzotriazole is interpreted as two distinct benzotriazole species on the surface. On the basis of this information a new structure for benzimidazole and benzotriazole on copper surfaces is proposed.
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页码:2 / 4
页数:3
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