The Efficiency of Carbon Dioxide and Hydrogen Sulphide Adsorption using Impregnated Granular Activated Carbon and Zeolite

In this work, adsorbents granular activated carbon (GAC), granular activated carbon with acetylene (CM/GAC) and zeolite A were applied for carbon dioxide (CO2) and hydrogen sulphide (H2S) gas removal. The adsorbents were characterised by scanning electron microscope (S.EM) and X-ray diftaction (ARD). Polyethyleneimine (PEI) in ethanol with initial concentration of 0.2 g l(-1) and 1 mol dm(-3) lithium nitrate (LiNO3) were prepared to improve the adsorption capacity. In the impregnation process, various adsorbents, i.e., GAC, CUD/GAC and zeolite A were placed in a vial containing 0.2 g l(-1) of PEI and 1 mol dm(-3) of LiNO3 solution, at different ratios ofadsorbent and various solutions of 30%W/W. The adsorbents (G4C, PEI/CVD/GAC:PEI/GAC, LiNO3/CVD/GAC:LiNO3/ GAC, zeolite 5A, PEI/zeolite 5A and LiNO3/zeolite 5A) were tested by using the synthetic biogas (45% CO2, 10% N2, 45% CH 4 and 105 mg dm(-3) of H2S). The performance of CO2 and H2S adsorption results have shown that PEI/CVD/GAC is the best adsorbent for low concentration of H2S and LiNO3/5A is the best adsorbent for CO2 adsorption. The purity of the outlet methane was 96.6%, 97.3%, 98.1%, 81.53%, 80.6% and 93.6% for zeolite 5A, LiNO3/5A, PEI/5A, GAG, LiNO3/CM/GAC and PEI/CM/GAC, respectively. The selectivity in the H 2 S/Clbratio of GAC is higher than zeolite 5A. The adsorption selectivity of the CO2/CH4 ratio of LiNO3/5A is higher than GAG.