CIDNP STUDIES ON THE PHOTOCHEMICAL-REACTION OF 4-METHYL-2-QUINOLINECARBONITRILE WITH OPTICALLY-ACTIVE (S)-2-PHENYLPROPIONIC OR (R)-2-PHENYLPROPIONIC ACID - NO EVIDENCE FOR THE CHIRAL-SYMMETRY BREAKING

被引：2

作者：

ALI, SS ^{[1
]}

MAEDA, K ^{[1
]}

AZUMI, T ^{[1
]}

机构：

[1] TOHOKU UNIV,FAC SCI,DEPT CHEM,SENDAI,MIYAGI 98077,JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 03期

关键词：

D O I：

10.1246/cl.1995.227

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photochemical reactions of 4-methyl-2-quinolinecarbonitrile (MQCN) with the enantiomers of 2-phenylpropionic acid (PPA) has been studied by CIDNP technique. The problem of chemical behavior discrimination of the enantiomers of PPA proposed by Hata(1) was examined. In contrast to the proposal of Hata, both (R) and (S) forms of PPA are shown to have radical intermediates in their reaction with MQCN.

引用

页码：227 / 228

页数：2

共 31 条

[1] PHOTOCHEMICAL-REACTION OF 4-METHYL-2-QUINOLINECARBONITRILE WITH OPTICALLY-ACTIVE (S)-2-PHENYLPROPIONIC ACID OR (R)-2-PHENYLPROPIONIC ACID - THE MAGNETIC-FIELD AND SOLVENT EFFECTS AND CHIRAL-SYMMETRY BREAKING
HATA, N
CHEMICAL PHYSICS, 1992, 162 (01) : 47 - 52
[2] PHOTOCHEMICAL-REACTION OF 4-METHYL-2-QUINOLINECARBONITRILE WITH OPTICALLY-ACTIVE (S)-2-PHENYLPROPIONIC ACID OR (R)-2-PHENYLPROPIONIC ACID - THE MAGNETIC-FIELD AND SOLVENT EFFECTS AND CHIRAL-SYMMETRY BREAKING - COMMENT
NAKAGAKI, R
CHEMICAL PHYSICS, 1994, 185 (03) : 405 - 411
[3] DOES A MAGNETIC-FIELD INDUCE OPTICAL-ACTIVITY IN PHOTOCHEMICAL-REACTION OF 4-METHYL-2-QUINOLINECARBONITRILE WITH OPTICALLY-ACTIVE (S)-(+)-2-PHENYLPROPIONIC ACID
FUJIWARA, Y
TANAKA, T
OHTANI, H
TANIMOTO, Y
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1994, 67 (09) : 2577 - 2579
[4] PHOTOCHEMICAL-REACTIONS OF 4-METHYL-2-QUINOLINECARBONITRILE WITH OPTICALLY-ACTIVE 2-PHENYLPROPIONIC ACIDS - THE MAGNETIC-FIELD AND SOLVENT EFFECTS
HATA, N
CHEMISTRY LETTERS, 1991, (01) : 155 - 158
[5] Chiral recognition of dihydroxyphenylalanine enantiomers with (R)/(S)-2-Phenylpropionic acid grafted PProDOT electrochemical sensors
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[6] Enantioselective photoreaction occurring in a chiral bimolecular crystal formed from acridine and R-(-)- or S-(+)-2-phenylpropionic acid
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TETRAHEDRON LETTERS, 1997, 38 (34) : 6063 - 6066
[7] ASYMMETRIC SYNTHESIS .3. STEREOSPECIFIC SYNTHESIS OF (R)-2-HYDROXY-2-PHENYLPROPIONIC ACID AND (R)- AND (S)-2-CYCLOHEXYL-2-HYDROXY-2-PHENYLACETIC ACID . CONFIGURATIONAL RELATIONSHIP BETWEEN (R)[-)-2-HYDROXY-2-PHENYLPROPIONIC ACID AND (S)(+)-2-PHENYLPROPIONIC ACID
INCH, TD
LEY, RV
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JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1968, (13): : 1693 - &
[8] PHOTOSUBSTITUTION REACTIONS OF 4-METHYL-2-QUINOLINECARBONITRILE WITH ARYLALKANOIC ACIDS - NO EVIDENCE FOR THE EXTERNAL MAGNETIC-FIELD EFFECTS OR CHIRAL-SYMMETRY BREAKING
NAKAGAKI, R
TAKAHIRA, O
YAMAOKA, M
KASHIMA, N
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1995, 68 (10) : 2803 - 2808
[9] Kinetic study on enantioselective resolution of (R,S)-2-phenylpropionic acid through Novozyme 435-catalyzed esterification
Yuan, Xin
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Xu, Weifeng
Tang, Kewen
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2019, 51 (07) : 520 - 527
[10] Studies on the chemical reactivity of 2-phenylpropionic acid 1-O-acyl glucuronide and S-Acyl-CoA thioester metabolitest
Li, C
Benet, LZ
Grillo, MP
CHEMICAL RESEARCH IN TOXICOLOGY, 2002, 15 (10) : 1309 - 1317

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