LANTHANIDE TRIFLUOROMETHANESULFONATES AS REUSABLE CATALYSTS - CATALYTIC FRIEDEL-CRAFTS ACYLATION

被引：153

作者：

KAWADA, A ^{[1
]}

MITAMURA, S ^{[1
]}

KOBAYASHI, S ^{[1
]}

机构：

[1] SCI UNIV TOKYO,FAC SCI,DEPT APPL CHEM,SHINJUKU KU,TOKYO 162,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 14期

关键词：

D O I：

10.1039/c39930001157

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Friedel-Crafts acylation of substituted benzenes proceeds smoothly by using a catalytic amount of a lanthanide trifluoromethanesulfonate [Ln(OTf)3], which is easily recovered from the reaction mixture and reused without a decrease in catalytic activity.

引用

页码：1157 / 1158

页数：2

共 14 条

[1]

BOKAYAHI S, 1991, CHEM LETT, P2187

[2] CATALYTIC FRIEDEL-CRAFTS ACYLATION OF AROMATIC-COMPOUNDS [J].

EFFENBERGER, F ;

EPPLE, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1972, 11 (04) :300-+

[3] FERRIC CHLORIDE-CATALYZED ACYLATION OF AROMATIC-COMPOUNDS WITH N-PHTHALOYL-ALPHA-AMINO ACYL CHLORIDES WITHOUT RACEMIZATION [J].

EFFENBERGER, F ;

STEEGMULLER, D .

CHEMISCHE BERICHTE-RECUEIL, 1988, 121 (01) :117-123

[4]

FOSBERG JH, 1987, J ORG CHEM, V52, P1017

[5] ACETYLATION OF TOLUENE WITH ACETYL-CHLORIDE AND BROMIDE CATALYZED BY CALCINED IRON SULFATE ACTIVATED BY EXPOSING TO A MIXTURE OF BENZYL-CHLORIDE AND TOLUENE [J].

HINO, M ;

ARATA, K .

CHEMISTRY LETTERS, 1978, (04) :325-326

[6] THE ALDOL REACTION OF SILYL ENOL ETHERS WITH ALDEHYDES IN AQUEOUS-MEDIA [J].

KOBAYASHI, S ;

HACHIYA, I .

TETRAHEDRON LETTERS, 1992, 33 (12) :1625-1628

[7] LANTHANIDE TRIFLUOROMETHANESULFONATES AS REUSABLE CATALYSTS - MICHAEL AND DIELS-ALDER REACTIONS [J].

KOBAYASHI, S ;

HACHIYA, I ;

TAKAHORI, T ;

ARAKI, M ;

ISHITANI, H .

TETRAHEDRON LETTERS, 1992, 33 (45) :6815-6818

[8] TRICHLOROLANTHANOID(LNCL3)-CATALYZED FRIEDEL-CRAFTS ALKYLATION REACTIONS [J].

MINE, N ;

FUJIWARA, Y ;

TANIGUCHI, H .

CHEMISTRY LETTERS, 1986, (03) :357-360

[9] A NOVEL CATALYST SYSTEM, ANTIMONY(V) CHLORIDE-LITHIUM PERCHLORATE (SBCL5-LICLO4), IN THE FRIEDEL-CRAFTS ACYLATION REACTION [J].

MUKAIYAMA, T ;

SUZUKI, K ;

HAN, JS ;

KOBAYASHI, S .

CHEMISTRY LETTERS, 1992, (03) :435-438

[10] THE CATALYTIC FRIEDEL-CRAFTS ACYLATION REACTION USING A CATALYST GENERATED FROM GACL3 AND A SILVER SALT [J].

MUKAIYAMA, T ;

OHNO, T ;

NISHIMURA, T ;

SUDA, S ;

KOBAYASHI, S .

CHEMISTRY LETTERS, 1991, (06) :1059-1062

← 1 2 →