ELECTRON-TRANSFER AT A PLANAR BILAYER-LIPID MEMBRANE INCORPORATED WITH 7,7,8,8-TETRACYANOQUINODIMETHANE STUDIED BY AC-IMPEDANCE SPECTROSCOPY

被引：29

作者：

YAMADA, H ^{[1
]}

SHIKU, H ^{[1
]}

MATSUE, T ^{[1
]}

UCHIDA, I ^{[1
]}

机构：

[1] TOHOKU UNIV,FAC ENGN,DEPT MOLEC CHEM & ENGN,AOBA KU,SENDAI,MIYAGI 980,JAPAN

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1993年 / 97卷 / 38期

关键词：

D O I：

10.1021/j100140a001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The heterogeneous electron-transfer rate constants for Co(phen)3(2+/3+) and Fe(CN)6(4-/3-) at the bilayer lipid membrane (BLM) saturated with tetracyanoquinodimethane (TCNQ) were respectively (3 +/- 1) X 10(-4) and <2 X 10(-8) cm/s, determined by ac impedance spectroscopy. The large difference in the rate constants was explained by hydrophobic interaction between the interior of the BLM and the redox species, by the electrostatic interaction between the negatively-charged surface and the redox species in solution, and by the difference in formal potential between TCNQ and the redox species.

引用

页码：9547 / 9549

页数：3

共 20 条

[1] MOLECULAR-ORIENTATION AND STRUCTURE IN EVAPORATED-FILMS OF 2-DODECYL-7,7,8,8-TETRACYANOQUINODIMETHANE, 2-PENTADECYL-7,7,8,8-TETRACYANOQUINODIMETHANE, AND 2-OCTADECYL-7,7,8,8-TETRACYANOQUINODIMETHANE STUDIED BY INFRARED AND RAMAN-SPECTROSCOPY
NAKAGOSHI, A
TERASHITA, S
OZAKI, Y
IRIYAMA, K
LANGMUIR, 1994, 10 (03) : 779 - 783
[2] Tetrathiafulvalene-7,7,8,8-Tetracyanoquinodimethane and Tetrathiafulvalene-2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane Organic Charge-Transfer Complexes: Reusable Catalysts for Electron-Transfer Reactions
Hoshyargar, Faegheh
O'Mullane, Anthony P.
CHEMCATCHEM, 2016, 8 (14) : 2335 - 2339
[3] Charge-transfer Complex Formed with Bowl-shaped Corannulene as Electron Donor and Planar 7,7,8,8-Tetracyanoquinodimethane as Electron Acceptor
Yoshida, Yukihiro
Isomura, Kazuhide
Nakamura, Yuto
Kishida, Hideo
Saito, Gunzi
CHEMISTRY LETTERS, 2015, 44 (05) : 709 - 711
[4] Photoinduced electron-transfer in porphyrin-quinone cyclophanes, 18 -: Porphyrin-cyclophanes with 7,7,8,8-tetracyanoquinodimethane as an especially strong electron-acceptor:: Syntheses, properties, electron-transfer interactions
Staab, HA
Weikard, J
Rückemann, A
Schwögler, A
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 1998, 1998 (12) : 2703 - 2712
[5] ELECTRON-SPIN RESONANCE STUDY OF THE CHARGE-TRANSFER COMPLEXES OF O-TOLIDINE WITH 7,7,8,8,-TETRACYANOQUINODIMETHANE AND 2,3,5,6-TETRAFLUORO-7,7,8,8-TETRACYANOQUINODIMETHANE
RATAICZAK, R
MARUO, T
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1984, 187 (APR): : 19 - CHED
[6] SPECTROPHOTOMETRIC STUDY OF THE CHARGE TRANSFER COMPLEXATION OF SOME AMINO ACID DERIVATIVE DRUGS AS ELECTRON DONORS WITH 7,7,8,8-TETRACYANOQUINODIMETHANE
Li, Sheng Yun
Guo, Qiao Lin
Yuan, Wen
Hou, Yu Cui
Du, Li Ming
BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA, 2010, 24 (01) : 21 - 30
[7] Potential dependence of electron-transfer rates at the interface between two immiscible electrolyte solutions: Reduction of 7,7,8,8-tetracyanoquinodimethane in 1,2-dichloroethane by aqueous ferrocyanide studied with microelectrochemical techniques
Zhang, J
Unwin, PR
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (10): : 2341 - 2347
[8] ELECTRON-TRANSFER REACTION BETWEEN DELTA-2,2'-BI-1,3-DITHIOLE (TTF) AND 7,7,8,8-TETRACYANOQUINODIMETHANE (TCNQ) - ELECTRON DONATING PROPERTY OF TTF
YAMAGISHI, A
IIDA, Y
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1980, 53 (05) : 1340 - 1343
[9] RATES OF REVERSIBLE ELECTRON-TRANSFER REACTION BETWEEN 7,7,8,8-TETRACYANOQUINODIMETHANE ANION RADICAL AND 2,3-DICHLORO-5,6-DICYANO-P-BENZOQUINONE IN ACETONITRILE
YAMAGISHI, A
CHEMISTRY LETTERS, 1975, (08) : 899 - 902
[10] 7,7,8,8-TETRACYANOQUINODIMETHANE CHEMI-LUMINESCENCE SENSITIZED BY RHODAMINE-B ON SURFACTANT BILAYER-MEMBRANE ASSEMBLIES FOR DETERMINATION OF SULFIDE BY A FLOW-INJECTION METHOD
QIAN, XX
GUO, YY
YAMADA, M
KOBAYASHI, E
SUZUKI, S
TALANTA, 1989, 36 (04) : 505 - 508

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