SYNTHESIS OF PT(II)-ETA-3-BENZYL COMPLEXES - CRYSTAL-STRUCTURE OF [PT(BU-TERT-2P(CH2)3PBU-TERT-2)(ETA-3-ANTI-1-MECHC6H4BR-4)][BF4]

被引：37
作者：
CRASCALL, LE
LITSTER, SA
REDHOUSE, AD
SPENCER, JL
机构：
[1] Department of Chemistry and Applied Chemistry, University of Salford, Salford
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 394卷 / 1-3期
关键词：
D O I：
10.1016/0022-328X(90)87277-K
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of bis(1,5-cyclooctadiene)platinum with 1,3-bis(di-t-butylphosphino)propane and various styrenes and subsequent protonation of the resultant platinum(0) alkene complexes affords a series of cationic complexes [Pt(Bu2tP(CH2)3PBu2t)(η3-anti-1-MeCHC6H4X)][BF4] (X = Br-3, Br-4 (2b), H, Me-4, MeO-4). These have been characterized by NMR spectroscopy and, in the case of 2b, by a single-crystal X-ray diffraction study. © 1990.
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页码：C35 / C38
页数：4
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