SOLUBILITY OF HYDROGEN CHLORIDE IN ICE

被引：20
作者：
KRISHNAN, PN
SALOMON, RE
机构：
[1] Department of Chemistry, Temple University, Commonwealth System of Higher Education, Philadelphia, PA
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 08期
关键词：
D O I：
10.1021/j100842a037
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A method has been devised to measure the equilibrium solubility of HCl in ice. Single crystals of ice were placed in contact with a polycrystalline disk of ice containing radioactive HCl. After a specified time, the diffusion profile was measured, and the solubility was determined by extrapolation to infinite time using Fick's laws of diffusion. Fickian diffusion was demonstrated, and the diffusion coefficient was determined.
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页码：2680 / &
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