NEW SIDE-GROUP LIQUID-CRYSTALLINE POLYMETHACRYLATES

被引：0
|
作者：
RODEKIRCH, G
RUBNER, J
ZSCHUPPE, V
WOLFF, D
SPRINGER, J
机构：
来源：
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS | 1993年 / 194卷 / 04期
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中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A new route of synthesis of liquid-crystalline polymethacrylates was investigated. The synthetic route involved side-group liquid-crystalline polymethacrylates (LCPMA) with a turned ester group between the aromatic rings in the central unit of mesogens (2) as compared with the usual LCPMA (1). For a series of compounds of this type the liquid-crystalline properties were investigated using differential scanning calorimetry, polarizing microscopy and X-ray diffraction techniques. Generally stable smectic phases were found for these isomeric LCPMA. The described synthetic route opens possibilities to form new polymers from a wide field of educts.
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页码：1125 / 1135
页数：11
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