TRANSFORMATION OF AN ALCOHOL IN THE PRESENCE OF A KETONE AS A MODEL REACTION TO CHARACTERIZE THE ACIDITY AND THE BASICITY OF OXIDE CATALYSTS

被引：25

作者：

BERKANI, M ^{[1
]}

LEMBERTON, JL ^{[1
]}

MARCZEWSKI, M ^{[1
]}

PEROT, G ^{[1
]}

机构：

[1] UFR SCI,CATALYSE CHIM ORGAN LAB,CNRS,UA 350,F-86022 POITIERS,FRANCE

来源：

CATALYSIS LETTERS | 1995年 / 31卷 / 04期

关键词：

ALCOHOL-KETONE HYDROGEN TRANSFER; ALCOHOL DEHYDRATION; ACID-BASE CATALYSTS; MAGNESIUM OXIDE; CS-EXCHANGED NAX ZEOLITES; ALUMINA; K-IMPREGNATED ALUMINA; ACID-BASE PROPERTIES;

D O I：

10.1007/BF00808604

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction of cyclopentanol in the presence of cyclohexanone at 350 degrees C over amorphous solids or zeolites led to alkenes and hydrogen transfer products. It was shown that these products were formed respectively on the acid sites and on the basic sites of the catalysts. Consequently, this reaction made it possible to estimate at the same time the acid and basic properties of the catalysts.

引用

页码：405 / 410

页数：6

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