SYNTHESIS OF NEW GRAFT POLYMERS VIA ANIONIC GRAFTING OF BETA-BUTYROLACTONE ON POLY(METHYL METHACRYLATE)

被引：38
|
作者：
KOWALCZUK, M [1 ]
ADAMUS, G [1 ]
JEDLINSKI, Z [1 ]
机构：
[1] POLISH ACAD SCI,INST POLYMER CHEM,PL-41800 ZABRZE,POLAND
来源：
MACROMOLECULES | 1994年 / 27卷 / 02期
关键词：
D O I：
10.1021/ma00080a035
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Novel graft polymers have been synthesized via an anionic grafting reaction of beta-butyrolactone (beta-BL) on poly(methyl methacrylate) (PMMA). It was found that partially saponified PMMA bearing carboxylate anions complexed by 18-crown-6 potassium counterion acts as a macroinitiator of beta-butyrolactone polymerization. As a result, graft polymers of PMMA with grafted poly(butyrolactone) side chains are produced in high yield over a wide graft composition range.
引用
收藏
页码：572 / 575
页数：4
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