ACIDITY AND CATALYTIC ACTIVITY OF MEAPSO-44 (ME = CO, MN, CR, ZN, MG), SAPO-44, AIPO4-5, AND AIPO4-14 MOLECULAR-SIEVES IN METHANOL DEHYDRATION

被引：51

作者：

HOCEVAR, S

BATISTA, J

KAUCIC, V

机构：

[1] Department of Catalysis and Chemical Reaction Engineering, Institute of Chemistry, 61115 Ljubljana, Hajdrihova 19

来源：

JOURNAL OF CATALYSIS | 1993年 / 139卷 / 02期

关键词：

D O I：

10.1006/jcat.1993.1030

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

SAPO-44 and the isomorphously substituted MeAPSO-44 (Me = Co, Mn, Cr, Zn, Mg) molecular sieves have been synthesized. The temperature-programmed desorption (TPD) spectra and the reaction rates of methanol dehydration have been measured on these samples in comparison with AlPO4-5 and AlPO4-14 samples. The acidity strength of samples has been determined qualitatively from the temperatures of dimethylether desorption peaks, and the following sequence has been obtained: MnAPSO-44 > CoAPSO-44 ≈ ZnAPSO-44 > MgAPSO-44 > CrAPSO-44 > SAPO-44 ≫ AlPO4-5 ≈ AlPO4-14. The following sequence of catalytic activity has been observed: AlPO4-14 > AlPO4-5 ≈ SAPO-44 > CoAPSO-44 > MnAPSO-44. The highest selectivity to ethene production among these catalysts has been found for CoAPSO-44. The selectivities to ethene of SAPO-44 and MeAPSO-44 (Me = Co, Mn, Cr) samples are about three times higher than the selectivities of SAPO-34 and MeAPSO-34 (Me = Co, Mn, Cr) samples. The selectivities of transition-metal-substituted MeAPSO-44 samples follow the Irving-Williams transition metal-ligand complex stability order. © 1993 Academic Press, Inc.

引用

页码：351 / 361

页数：11

共 19 条

[1]

Bennett J.M., 1998, STUD SURF SCI CAT, V37, P269, DOI [10.1016/S0167-2991(09)60604-2, DOI 10.1016/S0167-2991(09)60604-2]

[2]

Flanigen E. M., 1988, STUD SURF SCI CATAL, V37, P13

[3]

FLANIGEN EM, 1988, Patent No. 4738837

[4]

GREENWOOD NN, 1984, CHEM ELEMENTS, P1060

[5]

HOCEVAR S, 1992, J CATAL, V135, P518

[6] PREPARATION OF SILICO-ALUMINO-PHOSPHATES BY THE RAPID CRYSTALLIZATION METHOD AND THEIR CATALYTIC PERFORMANCE IN THE CONVERSION OF METHANOL TO LIGHT OLEFINS [J].

INUI, T ;

MATSUDA, H ;

OKANIWA, H ;

MIYAMOTO, A .

APPLIED CATALYSIS, 1990, 58 (02) :155-163

[7] HIGHLY SELECTIVE SYNTHESIS OF ETHENE FROM METHANOL ON A NOVEL NICKEL SILICOALUMINOPHOSPHATE CATALYST [J].

INUI, T ;

PHATANASRI, S ;

MATSUDA, H .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (03) :205-206

[8] STRUCTURE OF AN ALUMINOSILICOPHOSPHATE [J].

ITO, M ;

SHIMOYAMA, Y ;

SAITO, Y ;

TSURITA, Y ;

OTAKE, M .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1985, 41 :1698-1700

[9] CHARACTERISTICS AND PERFORMANCE OF SAPO-34 CATALYST FOR METHANOL-TO-OLEFIN CONVERSION [J].

LIANG, J ;

LI, HY ;

ZHAO, S ;

GUO, WG ;

WANG, RH ;

YING, ML .

APPLIED CATALYSIS, 1990, 64 (1-2) :31-40

[10]

Lok B.M., 1984, US Patent, Patent No. [4,440,871, 4440871, 4440,871]

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