EQUILIBRIA IN COMPLEXES OF N-HETEROCYCLIC MOLECULES .26. REACTIONS OF HYDROXIDE AND WATER WITH THE TRIS-(2,2'-BIPYRAZINE) IRON(II) AND TRIS-[2,2'-BIS-(5,6-DIHYDRO-4-H-1,3-OXAZINE)]IRON(II) IONS

被引：14

作者：

GILLARD, RD ^{[1
]}

KNIGHT, DW ^{[1
]}

WILLIAMS, PA ^{[1
]}

机构：

[1] UNIV WALES UNIV COLL CARDIFF,DEPT CHEM,CARDIFF CF1 1XL,S GLAMORGAN,WALES

来源：

TRANSITION METAL CHEMISTRY | 1979年 / 4卷 / 06期

关键词：

D O I：

10.1007/BF00623981

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of [Fe(bipyz)3]2+ (bipyz = 2,2′-bipyrazine) and [Fe(box)3]2+ [box = 2,2′-bis-(5,6-dihydro-4-H-1,3-oxazine] with H2O and HO- in aqueous solution have been followed. The [Fe(bipyz)3]2+ ion is attacked at the ligand with both nucleophiles and the ligand is cleaved. A similar reaction between HO- and [Fe(box)3]2+ is observed. Detailed kinetics for all reactions are reported. © 1979 Verlag Chemie, GmbH.

引用

页码：375 / 378

页数：4

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