RING-OPENING METATHESIS POLYMERIZATION OF [2.2]PARACYCLOPHANE-1,9-DIENE (PCPDE) TO POLY(P-PHENYLENE-VINYLENE) (PPV) AND COPOLYMERS WITH CYCLOPENTENE

被引：33

作者：

THORNCSANYI, E

HOHNK, HD

机构：

[1] Institut für Technische und Makromolekulare Chemie, Universität Hamburg, 2000 Hamburg 13

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1992年 / 76卷 / 1-3期

关键词：

Aromatic compounds - Aromatic polymers - Catalysts - Copolymers - Monomers - Olefins - Ring opening polymerization - Tungsten compounds;

D O I：

10.1016/0304-5102(92)80149-B

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The cyclic monomer [2.2]paracyclophane-1,9-diene (PCPDE) is directly polymerizable via ring-opening metathesis with the conventional catalyst system WCl6/2 epichlorohydrin/2 AlEt2Cl and the well-defined tungsten carbene [W(CHAr')(NAr)[OCMe-(CF3)2]2(THF)] (Ar=2,6-Me2C6H3,Ar'=o-MeOC6H4) (I) to poly(p-phenylene-vinylene) (PPV). PCPDE and 1,3,5,7-cyclooctatetraene form copolymers with cyclopentene using catalyst I.

引用

页码：101 / 105

页数：5

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