Calorimetric studies on Se0.68Ge0.22M0.10 (M = Cd, In, Pb) Chalcogenide Glasses

被引:0
作者
Mehta, N. [1 ]
Agarwal, P. [2 ]
Kumar, A. [1 ]
机构
[1] Harcourt Butler Technol Inst, Dept Phys, Kanpur 208002, Uttar Pradesh, India
[2] DBS Coll, Dept Phys, Kanpur, Uttar Pradesh, India
来源
TURKISH JOURNAL OF PHYSICS | 2005年 / 29卷 / 03期
关键词
Chalcogenide glasses; Differential Scanning Calorimetry; Activation energy of crystallization;
D O I
暂无
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Differential scanning calorimetry (DSC) is performed at different heating rates under non-isothermal wconditions to calculate the activation energy of crystallization Ec for chalcogenide glasses Se0.68Ge0.22M0.10 (M = Cd, In and Pb) using the well known Kissinger's relation, Matusita-Sakka theory and the method of Augis-Bennett. The overall mean bond energy < E > of these glassy alloys has been evaluated using theory of Tichy and Ticha. A good correlation has been found between Ec and < E >. This indicates that the overall mean bond energy plays an important role in the thermal crystallization of chalcogenide glasses.
引用
收藏
页码:193 / 200
页数:8
相关论文
共 27 条
[1]   DIELECTRIC BEHAVIOR OF GEXSE100-X AND GE22SE68M10 (M = AG, IN, PB, CD) GLASSY ALLOYS [J].
ARORA, R ;
KUMAR, A .
PHYSICA B, 1991, 175 (04) :381-388
[2]   CALCULATION OF AVRAMI PARAMETERS FOR HETEROGENEOUS SOLID-STATE REACTIONS USING A MODIFICATION OF KISSINGER METHOD [J].
AUGIS, JA ;
BENNETT, JE .
JOURNAL OF THERMAL ANALYSIS, 1978, 13 (02) :283-292
[3]  
Chiba R., 1998, J NONCRYST SOLIDS, V105, P105
[4]  
EI-Ocker M. M., 1998, INDIAN J PHYS PT-A, V72A, P31
[5]  
FANG X, 1997, PHYS REV LETT, V78, P4423
[6]   FILM PREPARATION AND STRUCTURE-ANALYSIS OF OPTICAL-RECORDING DOMAINS OF AMORPHOUS GE-SB-TE [J].
JIANG, FS ;
XU, YH ;
JIANG, RG ;
GAN, FX .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1995, 184 :51-56
[7]   On the crystallization kinetics of amorphous Se80In20-xPbx [J].
Khan, SA ;
Zulfequar, M ;
Husain, M .
SOLID STATE COMMUNICATIONS, 2002, 123 (10) :463-468
[8]   REACTION KINETICS IN DIFFERENTIAL THERMAL ANALYSIS [J].
KISSINGER, HE .
ANALYTICAL CHEMISTRY, 1957, 29 (11) :1702-1706
[9]   SPACE-CHARGE LIMITED CONDUCTION IN A-GE22SE68M10 (M = CD,IN,PB,TE) [J].
KUMAR, S ;
ARORA, R ;
KUMAR, A .
JOURNAL OF ELECTRONIC MATERIALS, 1993, 22 (06) :675-679
[10]  
Maharjan N. B., 2000, Indian Journal of Physics, Part A, V74A, P343