A REMARKABLE ACCELERATING EFFECT OF IODIDE-IONS IN THE PHOTOSTIMULATED PHOSPHONYLATION OF BROMOAROMATIC COMPOUNDS

被引：15

作者：

BOUMEKOUEZ, A ^{[1
]}

ABOUTJAUDET, E ^{[1
]}

COLLIGNON, N ^{[1
]}

SAVIGNAC, P ^{[1
]}

机构：

[1] ECOLE POLYTECH,DCPH,CHIM PHOSPHORE & MET TRANSIT LAB,F-91128 PALAISEAU,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 440卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)80208-F

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We find that 1 equiv. of NaI greatly accelerates the photostimulated substitution (S(RN) 1 mechanism) of bromobenzene, bromotoluenes and bromopyridines by diethylphosphite ion, in acetonitrile/tetrahydrofuran mixtures. Consequently, bromoaromatic compounds are suitable for preparative use.

引用

页码：297 / 301

页数：5

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