PICOSECOND TIME-RESOLVED VIBRATIONAL SPECTROSCOPY USING A REGENERATIVE AMPLIFIER

被引：14
作者：
JEDJU, TM
ROBERSON, MW
ROTHBERG, L
机构：
[1] ATandT Bell Laboratories, Murray Hill, NJ, 07974-0636
[2] Department of Physics, Middlebury College, Middlebury, VT
来源：
APPLIED OPTICS | 1992年 / 31卷 / 15期
关键词：
D O I：
10.1364/AO.31.002684
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
We demonstrate and characterize an apparatus for transient infrared spectroscopy with a 5-ps resolution. A visible pump and narrow-band mid-infrared probe are both derived from a source that is based on a pulsed Nd:YAG regenerative amplifier that operates at 540 Hz. We measure transient spectra in the range 1770-2250 cm-1 with a 1-cm-1 resolution and sensitivity to absorbance changes less than or equal to 1 x 10(-3). As an example, we present results from experiments to study ligand photodissociation from carboxymyoglobin in D2O.
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收藏
页码：2684 / 2691
页数：8
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