MOLECULAR-ENERGIES IN PARTLY CHARGED ORGANIC-SOLIDS

被引：19
作者：
SOOS, ZG
机构：
[1] Department of Chemistry, Princeton University, Princeton
来源：
CHEMICAL PHYSICS LETTERS | 1979年 / 63卷 / 01期
关键词：
D O I：
10.1016/0009-2614(79)80485-6
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The energies ΔED(γ) and ΔEA(-γ) for a partly charged organic donor, Dγ+, and organic acceptor, Aγ-, are discussed in terms of a three-point fit based on γ=-1,0, and 1, as used in atomic electronegativities. Apparent difficulties with the existence and stability of partly charged (γ ≈ 1 2) 1:1 DA solids are resolved on using improved ΔED (γ) and ΔEA(-γ) values instead of the more common linear estimates. © 1979.
引用
收藏
页码：179 / 183
页数：5
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