Reactive asymmetry of methyl iodide: Crossed beam study of the reaction of Rb with oriented CH3I molecules

被引：51

作者：

Beuhler, R. J., Jr.

Bernstein, R. E.

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

[2] Univ Wisconsin, Inst Theoret Chem, Madison, WI 53706 USA

来源：

CHEMICAL PHYSICS LETTERS | 1968年 / 2卷 / 03期

关键词：

D O I：

10.1016/0009-2614(68)85032-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Reported are asymmetry measurements as a function of scattering angle and degree of alignment which indicate that the ratio of differential reactive cross sections (in the backward (C.M.) direction) for the "favorable" versus "unfavorable" molecular orientations exceeds 3:1.

引用

页码：166 / 169

页数：4

共 13 条

[1] AMDUR I, 1966, CHEM KINETICS PRINCI
[2] OBSERVATION OF REACTIVE ASYMMETRY OF METHYL IODIDE . CROSSED BEAM STUDY OF REACTION OF RUBIDIUM WITH ORIENTED METHYL IODIDE MOLECULES
BEUHLER, RJ
BERNSTEIN, RB
KRAMER, KH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (22) : 5331 - +
[3] REACTIVE SCATTERING OF K ATOMS FROM ORIENTED CH3I MOLECULES
BROOKS, PR
JONES, EM
[J]. JOURNAL OF CHEMICAL PHYSICS, 1966, 45 (09) : 3449 - &
[4] DENCE JB, 1968, CHEM DYNAMICS
[5] ENTEMANN EA, 1967, DISCUSS FARADAY SOC, V14, P289
[6] MOLECULAR BEAMS AND A CHEMICAL REACTION - RESULTS FOR REACTION OF POTASSIUM WITH METHYL IODIDE SHOW HOW BEAM EXPERIMENTS AND THEORETICAL WORK CONTRIBUTE TO CHEMICAL KINETICS
GREENE, EF
ROSS, J
[J]. SCIENCE, 1968, 159 (3815) : 587 - &
[7] REACTIVE SCATTERING IN CROSSED MOLECULAR BEAMS - K ATOMS WITH CH3I AND C2H5I
HERSCHBACH, D
KWEI, GH
NORRIS, JA
[J]. JOURNAL OF CHEMICAL PHYSICS, 1961, 34 (05) : 1842 - &
[8] HERSCHBACH DR, 1962, DISCUSS FARADAY SOC, P149
[9] HERSCHBACH DR, 1966, MOLECULAR BEAMS, pCH9
[10] QUASICLASSICAL TRAJECTORY ANALYSIS FOR REACTION POTASSIUM ATOMS WITH ORIENTED METHYL IODIDE MOLECULES
KARPLUS, M
GODFREY, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (22) : 5332 - &

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