THE STRUCTURE OF [CO-2(CO)(5)(MU(2),ETA(4)-CPHCHCHCPH)] A COBALT ANALOG OF THE FERROLES

被引：6

作者：

MOLDES, I

PAPWORTH, T

ROS, J

ALVAREZLARENA, A

PINIELLA, JF

机构：

[1] UNIV AUTONOMA BARCELONA,DEPT QUIM,E-08193 BARCELONA,SPAIN

[2] UNIV AUTONOMA BARCELONA,UNITAT CRISTALLOG,E-08193 BARCELONA,SPAIN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 489卷 / 1-2期

关键词：

COBALT; CARBONYL; METALLACYCLE; ALKYNE; PI-BONDING; CLUSTER;

D O I：

10.1016/0022-328X(94)05301-Q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Co-2(CO)(5)(mu(2),eta(4)-CPhCHCHCPh)], a new cobaltacyclopentadiene dinuclear compound, was isolated and characterized by spectroscopic techniques. The X-ray structure of this compound has been determined.

引用

页码：C65 / C67

页数：3

共 10 条

[1]

BATTAGLIA LP, 1989, J ORGANOMET CHEM, V363, P209

[2]

BENNETT MA, 1987, INORG CHEM, V17, P1995

[3] A STRUCTURAL-ANALYSIS OF THE SEMIBRIDGING CARBONYL [J].

CRABTREE, RH ;

LAVIN, M .

INORGANIC CHEMISTRY, 1986, 25 (06) :805-812

[4]

Dickson R. S., 1974, ADV ORGANOMET CHEM, V12, P323, DOI DOI 10.1016/S0065-3055(08)60454-2

[5]

FEHLHAMMER WP, COMPREHENSIVE ORGANO, V4, P513

[6]

KEMMITT RD, 1982, COMPREHENSIVE ORGANO, V5, P177

[7] FORMATION OF METALLACYCLES FROM TERMINAL DIYNES WITH GEMINAL METHYL-GROUPS ALPHA TO THE TRIPLE BONDS - SYNTHESIS AND CRYSTAL-STRUCTURE OF CO2(CO)5[(HCCCME2)2NME], AN INTERMEDIATE IN COBALT-CATALYZED ORGANIC SYNTHESES [J].

PREDIERI, G ;

TIRIPICCHIO, A ;

CAMELLINI, MT ;

COSTA, M ;

SAPPA, E .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 423 (01) :129-139

[8] COBALT METALLACYCLES .12. REACTION OF COBALTACYCLOPENTADIENE WITH NONACARBONYLDIIRON AND OCTACARBONYLDICOBALT - FORMATION OF DINUCLEAR METAL-COMPLEXES [J].

YAMAZAKI, H ;

YASUFUKU, K ;

WAKATSUKI, Y .

ORGANOMETALLICS, 1983, 2 (06) :726-732

[9] CARBON CARBON BOND FORMATION AT DIIRON CENTERS .7. NEW ROUTES TO ANIONIC ALKENYL-BRIDGED DIIRON COMPLEXES, AND REACTIONS OF THE LATTER WITH PROPARGYL CHLORIDE [J].

YANEZ, R ;

ROS, J ;

MATHIEU, R .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 414 (02) :209-218

[10] FORMATION OF [FEM(ETA-C5H5)(CO)4(MU-CO)(MU-CR=CR'H)] (M = FE OR RU) COMPLEXES FROM THE REACTION OF [MH(ETA-C5H5)(CO)2] WITH [FE2(CO)9] AND ACETYLENES - X-RAY STRUCTURE OF [FERU(ETA-C5H5)(CO)4(MU-CO)(MU-CPH=CPHH)] [J].

YANEZ, R ;

ROS, J ;

MOLDES, I ;

MATHIEU, R ;

SOLANS, X ;

FONTBARDIA, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (10) :3147-3150

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