THE ASYMMETRIC METALATION OF CHIRAL ARYLALDEHYDE ACETAL CHROMIUM TRICARBONYL COMPLEXES

被引：45

作者：

KONDO, Y ^{[1
]}

GREEN, JR ^{[1
]}

HO, JW ^{[1
]}

机构：

[1] UNIV WINDSOR,DEPT CHEM & BIOCHEM,WINDSOR N9B 3P4,ONTARIO,CANADA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 26期

关键词：

D O I：

10.1021/jo00026a005

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The chiral chromium tricarbonyl complex of benzaldehyde acetal 2, derived from (+)-diethyl tartrate, can be metalated by n-BuLi and subsequently functionalized by various electrophiles with a minimum of 86% de.

引用

页码：7199 / 7201

页数：3

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