THEORETICAL AND EXPERIMENTAL STUDIES ON THE PERISELECTIVITY OF THE CYCLOADDITION REACTION BETWEEN ACTIVATED KETENES AND CONJUGATED IMINES

被引：4
|
作者：
ARRASTIA, I
ARRIETA, A
UGALDE, JM
COSSIO, FP
LECEA, B
机构：
[1] EUSKAL HERRIKO UNIBERTSITATEA,FAK KIM,E-20080 SAN SEBASTIAN,SPAIN
[2] EUSKAL HERRIKO UNIBERTSITATEA,FAK FARM,E-01007 VITORIA,SPAIN
来源：
TETRAHEDRON LETTERS | 1994年 / 35卷 / 42期
关键词：
D O I：
10.1016/S0040-4039(00)77382-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Theoretical and experimental studies on the cycloaddition between methoxyketene and a model conjugated imine predict the preferential formation of the [2+2] cycloadduct. A configuration interaction level of theory is required to reproduce correctly the observed periselectivity.
引用
收藏
页码：7825 / 7828
页数：4
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