RADIATION-INDUCED POLYMERIZATION OF 2-METHYL-5-VINYL TETRAZOLE IN BULK UNDER THE ACTION OF GAMMA-IRRADIATION

被引：0
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作者：
GOVORKOV, AT
MURYSHKINA, YV
KHOKHLOVA, GP
BANNOVA, YA
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来源：
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A | 1991年 / 33卷 / 06期
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O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Radiation-induced polymerization of 2-methyl-5-vinyl tetrazole in bulk has been studied by IR-spectroscopy, capillary viscometry, GPC, ESR and gas chromatography methods and its radical mechanism has been proved. The process is accompanied by opening of the tetrazole ring and by the elimination of nitrogen with the radiation-chemical yield being equal to 9.6 molecules per 100 eV. The formed polymethylvinyl tetrazole is the amorphous polymer with the same parameters as a polymer synthesized with <<substance>> initiation.
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页码：1234 / 1238
页数：5
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