OXIDATIVE CLEAVAGE OF 2-SUBSTITUTED CYCLOALKANE-1,3-DIONES AND OF CYCLIC BETA-KETOESTERS BY COPPER PERCHLORATE/OXYGEN

被引：40

作者：

COSSY, J

BELOTTI, D

BELLOSTA, V

BROCCA, D

机构：

[1] Laboratoire de Chimie Organique, Associé au CNRS, ESPCI, 75231 Paris Cédex 05

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 33期

关键词：

2-SUBSTITUTED CYCLOALKANE-1,3-DIONE; CYCLIC BETA-KETOESTER; COPPER PERCHLORATE HEXAHYDRATE; OXYGEN; OXIDATIVE CLEAVAGE; (OMEGA-1); OMEGA-DIOXOCARBOXYLIC ACIDS; (OMEGA-1)-OXOALKANEDIOIC ACIDS MONOESTERS;

D O I：

10.1016/0040-4039(94)88083-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A preparative method for the synthesis of omega-1), omega-dioxocarboxylic acids and (omega-1)-oxoalkanedioic acids monoesters by respective oxidative cleavage of 2-substituted cycloalkane-1,3-diones and cyclic beta-ketoesters, by copper perchlorate in acetonitrile in an oxygen atmosphere, is reported.

引用

页码：6089 / 6092

页数：4

共 18 条

[1]

ATLAMSANI A, 1993, SYNTHESIS-STUTTGART, P79

[2] OXIDATION OF 2-METHYLCYCLOHEXANONE AND CYCLOHEXANONE BY DIOXYGEN CATALYZED BY VANADIUM-CONTAINING HETEROPOLYANIONS [J].