THERMOLYSIS OF METHOXYMETHYLSILANES .I. FORMATION OF METHOXYCARBENE

被引：28
作者：
ATWELL, WH
WEYENBER.DR
UHLMANN, JG
机构：
[1] Organometallic Research Laboratory, Dow Corning Corporation, Midland
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 08期
关键词：
D O I：
10.1021/ja01036a027
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A unique synthesis of (dimethoxymethyl)trimethoxysilane (I) is described. Compound I undergoes a low-temperature thermolysis to give tetramethoxysilane and methoxycarbene. Kinetic evidence is presented which demonstrates the formation of free methoxycarbene. Methoxycarbene generated via this method was shown to react with methanol, vinylsilanes, silicon hydrides, and stereospecincally with olefins. © 1969, American Chemical Society. All rights reserved.
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页码：2025 / &
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