ELECTROCHEMICAL SYNTHESIS OF METAL(II) COMPLEXES OF SCHIFF-BASES - THE CRYSTAL-STRUCTURE OF ACETONITRILE-BIS(2-[(2-PYRROLE)METHYLIMINO]-4,6-DIMETHYLPHENOLATO(ZINC(II)

被引：37
作者：
CASTRO, JA
ROMERO, J
GARCIAVAZQUEZ, JA
MACIAS, A
SOUSA, A
机构：
[1] UNIV SANTIAGO,DEPT QUIM INORGAN,SANTIAGO,SPAIN
[2] RHEIN WESTFAL TH AACHEN,INST ANORGAN CHEM,W-5100 AACHEN,GERMANY
来源：
POLYHEDRON | 1993年 / 12卷 / 11期
关键词：
D O I：
10.1016/S0277-5387(00)84331-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The electrochemical oxidation of anodic metals (Co, Ni, Cu, Zn and Cd) in acetonitrile solution containing a Schiff base (H-2L) derived from H-pyrrole-2-carbaldehyde and a substituted o-aminophenol yielded the complexes M(HL)2 and acetonitrile-bis{2-[(2-pyrrole)methyliminol-4,6-dimethylphenolato}zinc(II). X-ray data show the latter to have a distorted bipyramidal coordination polyhedron that does not include the pyrrole nitrogen atoms.
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页码：1391 / 1397
页数：7
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共 22 条
  • [1] COMPLEXATION OF METAL-SALTS WITH MACROCYCLIC POLYETHERS IN APROTIC-SOLVENTS - CRYSTAL-STRUCTURES OF IONIC [ZN.15-CROWN-5.2L]2+[ZN2CL6]2- (L = CH3CN, THF), [ZNCL.15-CROWN-5.6']2+[ZN2CL6]2- (L' = H2O, CH3COCH3) AND MOLECULAR ZNCL2.18-CROWN-6.H2O AND ZNCL2.2CH3CN COMPLEXES
    BELSKY, VK
    STRELTSOVA, NR
    BULYCHEV, BM
    STOROZHENKO, PA
    IVANKINA, LV
    GORBUNOV, AI
    [J]. INORGANICA CHIMICA ACTA, 1989, 164 (02) : 211 - 220
  • [2] BERTHIER G, 1966, CHEM CARBONYL GROUP
  • [3] BROWN JN, 1972, J AM CHEM SOC, V92, P7436
  • [4] SYNTHESIS OF NICKEL(II), COPPER(II), ZINC(II), AND CADMIUM(II) COMPLEXES OF 2-[(2-MERCAPTOPHENYL)IMINOMETHYL]PYRROLE AND 2-[(2-MERCAPTOETHYL)-IMINOMETHYL]PYRROLE BY THE ELECTROCHEMICAL CLEAVAGE OF A DISULFIDE BOND - THE CRYSTAL-STRUCTURE OF BIS(2-[(PYRROL-2-YL)METHYLENEAMINO]THIOPHENOLATO-S,N)ZINC(II)
    CASTRO, J
    ROMERO, J
    GARCIAVAZQUEZ, JA
    DURAN, ML
    CASTINEIRAS, A
    SOUSA, A
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (11): : 3255 - 3258
  • [5] ELECTROCHEMICAL SYNTHESIS OF METAL-COMPLEXES OF SCHIFF-BASES - THE CRYSTAL-STRUCTURE OF BIS(2-[(4-METHYLPHENYL)IMINOMETHYL]PYRROLATO)COPPER(II)
    CASTRO, JA
    ROMERO, J
    GARCIAVAZQUEZ, JA
    CASTINEIRAS, A
    DURAN, ML
    SOUSA, A
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1992, 615 (09): : 155 - 160
  • [6] ELECTROCHEMICAL SYNTHESIS OF COBALT(II) AND COBALT(III) COMPLEXES OF SCHIFF-BASES - THE CRYSTAL-STRUCTURE OF TRIS(2-[(2-METHYLPHENYL)IMINOMETHYL]PYRROLATO)COBALT(III)
    CASTRO, JA
    ROMERO, J
    GARCIAVAZQUEZ, JA
    DURAN, ML
    SOUSA, A
    CASTELLANO, EE
    ZUKERMANSCHPECTOR, J
    [J]. POLYHEDRON, 1992, 11 (02) : 235 - 241
  • [7] ELECTROCHEMICAL SYNTHESIS OF NICKEL(II) COMPLEXES OF SCHIFF-BASES - THE CRYSTAL-STRUCTURE OF 2,2'-BIPYRIDINE BIS(2-[(PHENYL)IMINOMETHYL]PYRROLATO)NICKEL(II)
    CASTRO, JA
    VILASANCHEZ, JE
    ROMERO, J
    GARCIAVAZQUEZ, JA
    DURAN, ML
    SOUSA, A
    CASTELLANO, EE
    ZUKERMANSCHPECTOR, J
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1992, 612 (06): : 83 - 88
  • [8] ELECTROCHEMICAL SYNTHESIS OF CO-COMPLEX, NI-COMPLEX AND ZN-COMPLEX WITH 2-PYRROLE-[N-(O-HYDROXYPHENYL)METHYLIMINES] - THE CRYSTAL-STRUCTURE OF 2,2'-BIPYRIDINE BIS(2-[(2-PYRROLE)METHYLIMINO]5-METHYLPHENOLATO)NICKEL(II)
    CASTRO, JA
    ROMERO, J
    GARCIAVAZQUEZ, JA
    CASTINEIRAS, A
    SOUSA, A
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1993, 619 (03): : 601 - 607
  • [9] ELECTROCHEMICAL SYNTHESIS OF CADMIUM(II) COMPLEXES OF SCHIFF-BASES - THE CRYSTAL-STRUCTURE OF 2,2'-BIPYRIDINE BIS(2-[(2-METHOXYPHENYL)-IMINOMETHYL]PYRROLATO)CADMIUM(II)
    CASTRO, JA
    ROMERO, J
    GARCIAVAZQUEZ, JA
    SOUSA, A
    CASTELLANO, EE
    ZUKERMANSCHPECTOR, J
    [J]. POLYHEDRON, 1993, 12 (01) : 31 - 36
  • [10] COORDINATION CHEMISTRY OF SAMARIUM(II) - X-RAY CRYSTAL-STRUCTURES OF SMI2(NCCME3)2 AND SMI2[O(CH2CH2OME)2]2. THE 1ST EXAMPLE OF A BENT M-N=C STRUCTURE
    CHEBOLU, V
    WHITTLE, RR
    SEN, A
    [J]. INORGANIC CHEMISTRY, 1985, 24 (19) : 3082 - 3085
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