OXIDATION OF ORTHO-NITROTOLUENE TO ORTHO-NITROBENZALDEHYDE WITH ELECTROGENERATED COBALTIC SULFATE

被引：20

作者：

COMNINELLIS, C

PLATTNER, E

JAVET, P

机构：

[1] Institut de Génie chimique, Ecole Polytechnique Fédérale de Lausanne Ecublens, Lausanne

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1979年 / 9卷 / 06期

关键词：

D O I：

10.1007/BF00614970

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Indirect electrochemical oxidation of o-nitrotoluene to o-nitrobenzaldehyde by Co (III) has been studied. The highest aldehyde yield (∼ 80%) is obtained in dispersing a 70-fold excess of o-nitrotoluene in a solution of CO2(SO4)3 in 60% H2SO4 at 12° C. The influence of acid concentration, excess of nitrotoluene and presence of catalyst are discussed and found to be compatible with a mechanism proposed by Bawn. © 1979 Chapman and Hall Ltd.

引用

页码：753 / 755

页数：3

共 8 条

[1] BAWN CE, 1951, J CHEM SOC, V343
[2] COMNINELLIS C, UNPUBLISHED
[3] EBERSON L, 1971, ORGANIC ELECTROCHEMI
[4] Fleischmann M., 1971, J APPL ELECTROCHEM, V1, P1, DOI DOI 10.1007/BF00615740
[5] ELECTROLYTICALLY REGENERATED MANGANIC SULFATE FOR THE OXIDATION OF AROMATIC HYDROCARBONS .2. OXIDATION OF XYLENES TO TOLUALDEHYDES
RAMASWAMY, R
VENKATACHALAPATHY, MS
UDUPA, HVK
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1963, 110 (03) : 202 - 204
[6] SWANN S, 1939, J AM CHEM SOC, V53, P400
[7] SYPER L, 1967, TETRAHEDRON LETT, V42, P4193
[8] Syper L., 1966, TETRAHEDRON LETT, V7, P4493

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