OXIDATIVE ADDITION OF CHLOROBENZENE ON AN IRON-CYCLOPENTADIENYL CATION TO A LOW-VALENT PALLADIUM COMPLEX

被引：17

作者：

AOKI, T

ISHII, Y

MIZOBE, Y

HIDAI, M

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 04期

关键词：

D O I：

10.1246/cl.1991.615

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxidative addition of the coordinated chlorobenzene in [CpFe(C6H5Cl)][PF6] to Pd(PPh3)4 proceeds under THF-reflux conditions to give [CpFe{eta-6-[PdCl(PPh3)2]C6H5}][PF6]. X-ray analysis of this complex revealed that the phenyl ring is sigma-bound to Pd and pi-bound to Fe, and that the palladium center takes the cis-configuration. This complex reacts with CO/MeOH, CO/HNEt2, styrene, and methyl acrylate to give methyl benzoate, N,N-diethylbenzamide, stilbene, and methyl cinnamate, respectively, after photolysis.

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页码：615 / 618

页数：4

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共 20 条

[1] ORGANO IRON COMPLEXES OF AROMATIC-COMPOUNDS - APPLICATIONS IN SYNTHESIS [J].

ASTRUC, D .

TETRAHEDRON, 1983, 39 (24) :4027-4095

[2]

BOGDANOVIC B, 1979, ANGEW CHEM, V91, P745

[3] BIMETALLIC ACTIVATION IN HOMOGENEOUS CATALYSIS .2. FORMATION OF ALPHA-OXO AMIDE BY PALLADIUM-CATALYZED DOUBLE CARBONYLATION OF THE TRICARBONYL (CHLOROBENZENE) CHROMIUM COMPLEX [J].

DANY, F ;

MUTIN, R ;

LUCAS, C ;

DUFAUD, V ;

THIVOLLECAZAT, J ;

BASSET, JM .

JOURNAL OF MOLECULAR CATALYSIS, 1989, 51 (02) :L15-L20

[4] CONFORMATIONAL VARIABILITY IN PI-COMPLEXES OF HEXAETHYLBENZENE - CRYSTAL AND MOLECULAR-STRUCTURE OF [(C6ET6)(C5H5)FE]BPH4 [J].

DUBOIS, RH ;

ZAWOROTKO, MJ ;

WHITE, PS .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 362 (1-2) :155-161

[5] ORGANOMETALLIC ELECTRON RESERVOIRS .7. ONE-STEP MULTIPLE FORMATION OF C-C BONDS IN CPFE+(ARENE) SANDWICHES AND UNUSUAL C6ET6 GEOMETRY IN THE X-RAY CRYSTAL-STRUCTURE OF CPFE+(ETA-6C6ET6)PF6- [J].

HAMON, JR ;

SAILLARD, JY ;

LEBEUZE, A ;

MCGLINCHEY, MJ ;

ASTRUC, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (26) :7549-7555

[6] CHROMIUM TRICARBONYL FACILITATED NUCLEOPHILIC AROMATIC-SUBSTITUTION BY METAL-CARBONYL ANIONS - THE SYNTHESIS AND MOLECULAR-STRUCTURE OF A NEW CLASS OF BIMETALLIC PI-ARENE COMPLEXES [J].

HEPPERT, JA ;

MORGENSTERN, MA ;

SCHERUBEL, DM ;

TAKUSAGAWA, F ;

SHAKER, MR .

ORGANOMETALLICS, 1988, 7 (08) :1715-1723

[7] TETRACARBONYL FERRATE DERIVATIVES OF (ETA-6-ARENE)CR(CO)3 - NEW REAGENTS FOR CARBON CARBON BOND FORMATION [J].

HEPPERT, JA ;

THOMASMILLER, ME ;

SWEPSTON, PN ;

EXTINE, MW .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (04) :280-282

[8] TRANS-BROMO(2-PYRIDYL, 3-PYRIDYL, AND 4-PYRIDYL)-BIS(TRIETHYLPHOSPHINE)PALLADIUM(II)COMPLEXES [J].

ISOBE, K ;

KAI, E ;

NAKAMURA, Y ;

NISHIMOTO, K ;

MIWA, T ;

KAWAGUCHI, S ;

KINOSHITA, K ;

NAKATSU, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (07) :2475-2476

[9] MOLECULAR ENCAPSULATION OF TRANSITION-METAL COMPLEXES IN CYCLODEXTRINS .1. SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [(ETA-5-C5H5)FE(ETA-6-C6H6)]PF6.2-ALPHA-CD.8H2O [J].

KLINGERT, B ;

RIHS, G .

ORGANOMETALLICS, 1990, 9 (04) :1135-1141

[10] MECHANISTIC FEATURES OF SNAR REACTIONS OF NEUTRAL AND CATIONIC METAL-COMPLEXED HALOGENOBENZENES WITH METHOXIDE [J].

KNIPE, AC ;

MCGUINNESS, SJ ;

WATTS, WE .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (19) :842-843