IMINO CARBENE COMPLEXES OF TUNGSTEN AND CHROMIUM AS SYNTHONS FOR NITRILE YLIDES IN REACTIONS WITH ALKYNES, ALKENES, NITRILES, AND ALDEHYDES

被引：19
作者：
DRAGISICH, V
WULFF, WD
HOOGSTEEN, K
机构：
[1] UNIV CHICAGO,SEARLE CHEM LAB,DEPT CHEM,CHICAGO,IL 60637
[2] MERCK & CO INC,DEPT BIOPHYS CHEM,RAHWAY,NJ 07065
来源：
ORGANOMETALLICS | 1990年 / 9卷 / 11期
关键词：
D O I：
10.1021/om00161a009
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The stable and isolable imino carbene complexes of chromium and especially tungsten are found to be synthons for nitrile ylides and have the advantage that the range of 1,3-dipolarophiles is not limited to electron acceptors but is broad enough to include electronically neutral as well as electron-rich systems. © 1990, American Chemical Society. All rights reserved.
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页码：2867 / 2870
页数：4
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