IMINO CARBENE COMPLEXES OF TUNGSTEN AND CHROMIUM AS SYNTHONS FOR NITRILE YLIDES IN REACTIONS WITH ALKYNES, ALKENES, NITRILES, AND ALDEHYDES

被引：19
作者：
DRAGISICH, V
WULFF, WD
HOOGSTEEN, K
机构：
[1] UNIV CHICAGO,SEARLE CHEM LAB,DEPT CHEM,CHICAGO,IL 60637
[2] MERCK & CO INC,DEPT BIOPHYS CHEM,RAHWAY,NJ 07065
来源：
ORGANOMETALLICS | 1990年 / 9卷 / 11期
关键词：
D O I：
10.1021/om00161a009
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The stable and isolable imino carbene complexes of chromium and especially tungsten are found to be synthons for nitrile ylides and have the advantage that the range of 1,3-dipolarophiles is not limited to electron acceptors but is broad enough to include electronically neutral as well as electron-rich systems. © 1990, American Chemical Society. All rights reserved.
引用
收藏
页码：2867 / 2870
页数：4
相关论文
共 54 条
[1]   REINVESTIGATION OF THE PICTET-GAMS ISOQUINOLINE SYNTHESIS .1. CONSEQUENCES OF OXAZOLINE RATHER THAN ISOQUINOLINE FORMATION [J].
ARDABILCHI, N ;
FITTON, AO ;
FROST, JR ;
OPPONGBOACHIE, FK ;
HADI, AHBA ;
SHARIF, AM .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1979, (02) :539-543
[2]   ORGANIC-SYNTHESIS WITH TRANSITION-METAL COMPLEXES .45. 3-HYDROXYPYRIDINES, 1H-PYRROLES AND 2-HYDROXYPYRROLE DERIVATIVES FROM AMINOCARBENE CHROMIUM COMPLEX AND ALKYNE [J].
AUMANN, R ;
HEINEN, H .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 389 (01) :C1-C6
[3]   ORGANIC-SYNTHESIS WITH TRANSITION-METAL COMPLEXES .49. PYRROLES FROM AMINO CARBENE CHROMIUM COMPLEX AND ALKYNES - SYNTHESIS OF A NEW BETA-TRIPYRRANE AND A CYCLIC BETA-TRISPYRROLE [J].
AUMANN, R ;
HEINEN, H .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 391 (01) :C7-C11
[4]  
AUMANN R, 1990, CHEM BER, P123
[5]   1-NAPHTHYLCARBENE - SPECTROSCOPY, KINETICS, AND MECHANISMS [J].
BARCUS, RL ;
HADEL, LM ;
JOHNSTON, LJ ;
PLATZ, MS ;
SAVINO, TG ;
SCAIANO, JC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (14) :3928-3937
[6]   REDUCTION OF OXIMES AND ALIPHATIC NITROCOMPOUNDS TO IMINES FOR FURTHER INSITU REACTIONS - A NOVEL SYNTHESIS OF PYRROLES AND PYRROLIN-2-ONES [J].
BARTON, DHR ;
MOTHERWELL, WB ;
SIMON, ES ;
ZARD, SZ .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1986, (12) :2243-2252
[7]   A NOVEL CLASS OF NITRILE YLIDE [J].
BOSSIO, R ;
MARCACCINI, S ;
PEPINO, R .
TETRAHEDRON LETTERS, 1986, 27 (38) :4643-4646
[8]   SYNTHESIS OF 4-ALKOXY-1,3-OXAZOL-5(2H)-ONES, PRECURSORS OF 1-ALKOXY-SUBSTITUTED NITRILE YLIDES [J].
BOZHKOVA, N ;
HEIMGARTNER, H .
HELVETICA CHIMICA ACTA, 1989, 72 (04) :825-837
[9]   REACTIONS WITH DELTA-4-1,4,2LAMBDA-5-OXAZAPHOSPHOLINES .11. THERMOLYSIS OF 3,3-BIS(TRIFLUOROMETHYL)-DELTA-4-1,4,2LAMBDA-5-OXAZAPHOSPHOLINES IN PRESENCE OF ENOL ETHERS AND 1-DIETHYLAMINO-1-PROPYNE [J].
BURGER, K ;
ROTH, WD ;
EINHELLIG, K ;
HATZELMANN, L .
CHEMISCHE BERICHTE-RECUEIL, 1975, 108 (08) :2737-2749
[10]  
BURGER K, 1984, CHEM BER, V109, P1984
123456