WATER-VAPOR DEPENDENCE OF THE KINETICS OF THE CH3O2-CH3O2 REACTION

被引：16
|
作者：
KAN, CS
CALVERT, JG
机构：
来源：
CHEMICAL PHYSICS LETTERS | 1979年 / 63卷 / 01期
关键词：
D O I：
10.1016/0009-2614(79)80469-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Flash spectroscopic studies of CH3O2 show that complexation between H2O and CH3O2 does occur significantly in the gas phase at high humidities. However this interaction does not alter significantly the rate constant for the second order decay of the CH3O2 radicals. This behavior is in constrast with that observed for the HO2 radical. © 1979.
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页码：111 / 114
页数：4
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