ELECTROCHEMISTRY OF ORGANOPHOSPHORUS COMPOUNDS .2. ELECTROREDUCTION OF TRIPHENYLPHOSPHINE AND TRIPHENYLPHOSPHINE OXIDE

被引：63

作者：

SANTHANAM, KS

BARD, AJ

机构：

[1] Department of Chemistry, University of Texas, Austin

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1968年 / 90卷 / 05期

关键词：

D O I：

10.1021/ja01007a005

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrochemical reduction of triphenylphosphine (TPP) and triphenylphosphine oxide (TPPO) has been investigated using polarography, cyclic voltammetry, coulometry, and product analysis. The reduction of TPP proceeds by a one-electron transfer to form the anion radical which undergoes cleavage of a phenyl group. © 1968, American Chemical Society. All rights reserved.

引用

收藏

页码：1118 / +

页数：1

相关论文

共 17 条

[1]

BEZUGLYI VD, 1965, SOV ELECTROCHEM, V1, P1279

[2] REACTION OF TRIPHENYLPHOSPHINE WITH ALKALI METALS IN TETRAHYDROFURAN [J].

BRITT, AD ;

KAISER, ET .

JOURNAL OF PHYSICAL CHEMISTRY, 1965, 69 (08) :2775-&

[3]

CHAPMAN D, 1963, J CHEM SOC, P3140

[4] FREE RADICALS INVOLVING PHOSPHORUS [J].

COWLEY, AH ;

HNOOSH, MH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (11) :2595-&

[5] ORGANOMETALLIC ELECTROCHEMISTRY .3. ORGANOMETALLIC ANIONS DERIVED FROM GROUP V ELEMENTS [J].

DESSY, RE ;

CHIVERS, T ;

KITCHING, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (03) :467-&

[6] ESR STUDY OF TRIPHENYLPHOSPHINE ANION [J].

HANNA, MW .

JOURNAL OF CHEMICAL PHYSICS, 1962, 37 (03) :685-&

[7] REACTION OF AROMATIC PHOSPHINE OXIDES WITH ALKALI METALS [J].

HOFFMANN, AK ;

TESCH, AG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (20) :5519-5520

[8] THE ULTRAVIOLET ABSORPTION SPECTRA OF ARYLPHOSPHONIC AND DIARYLPHOSPHINIC ACIDS [J].

JAFFE, HH ;

FREEDMAN, LD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1952, 74 (04) :1069-1071

[9] POLAROGRAPHY AND VOLTAMMETRY IN DIMETHYLSULFOXIDE [J].

KOLTHOFF, IM ;

REDDY, TB .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1961, 108 (10) :980-985

[10] TRACER DIFFUSION COEFFICIENTS OF NAPHTHALENE BIPHENYL AND ANTHRACENE [J].

MILLER, TA ;

PRATER, B ;

LEE, JK ;

ADAMS, RN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (01) :121-&