COMPOSITION AND STRUCTURE OF THE ANODIC FILMS ON TITANIUM IN AQUEOUS-SOLUTIONS

被引:89
作者
PANKUCH, M
BELL, R
MELENDRES, CA
机构
[1] ARGONNE NATL LAB,DIV MAT SCI,ARGONNE,IL 60439
[2] ARGONNE NATL LAB,DIV CHEM TECHNOL,ARGONNE,IL 60439
关键词
RAMAN SPECTROSCOPY; TITANIUM OXIDE FILM; ANODIC FILMS ON TITANIUM; COMPOSITION; STRUCTURE;
D O I
10.1016/0013-4686(93)85098-J
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Surface-enhanced Raman spectra of the amorphous him on titanium have been obtained for the first time. The anodic corrosion him at low potentials is identified to be highly disordered TiO2 with some Ti2O3 also present. The presence of the anatase and rutile modifications of TiO2 at high voltages (greater than or equal to 80 V) is confirmed.
引用
收藏
页码:2777 / 2779
页数:3
相关论文
共 19 条
[1]   ANODIC DISSOLUTION OF TITANIUM IN SULFURIC ACID [J].
ARMSTRONG, RD ;
HARRISON, JA ;
THIRSK, HR ;
WHITFIELD, R .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1970, 117 (08) :1003-+
[2]   INSITU RAMAN-SPECTRA OF ANODICALLY FORMED TITANIUM-DIOXIDE LAYERS IN SOLUTIONS OF H2SO4, KOH, AND HNO3 [J].
ARSOV, LD ;
KORMANN, C ;
PLIETH, W .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (10) :2964-2970
[3]   ELECTROCHEMISTRY OF FRESHLY-GENERATED TITANIUM SURFACES .1. SCRAPED ROTATING-DISK EXPERIMENTS [J].
BECK, TR .
ELECTROCHIMICA ACTA, 1973, 18 (11) :807-814
[4]   REVERSIBLE OPTICAL CHANGES WITHIN ANODIC OXIDE-FILMS ON TITANIUM AND NIOBIUM [J].
DYER, CK ;
LEACH, JSL .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1978, 125 (01) :23-29
[5]   BREAKDOWN AND EFFICIENCY OF ANODIC OXIDE-GROWTH ON TITANIUM [J].
DYER, CK ;
LEACH, JSL .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1978, 125 (07) :1032-1038
[6]   APPLICATION OF THE ELECTROREFLECTANCE TECHNIQUE TO A 3-MEDIUM SYSTEM [J].
FROELICHER, M ;
HUGOTLEGOFF, A ;
JOVANCICEVIC, V .
THIN SOLID FILMS, 1981, 82 (01) :81-88
[7]   OBTAINING SURFACE-ENHANCED RAMAN-SPECTRA FROM THE PASSIVE FILM ON IRON [J].
GUI, J ;
DEVINE, TM .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (05) :1376-1384
[8]   A NOTE ON THE PASSIVE ACTIVE TRANSITION OF TITANIUM IN SULFURIC-ACID [J].
HARRISON, JA ;
WILLIAMS, DE .
ELECTROCHIMICA ACTA, 1982, 27 (07) :891-895
[9]   STRUCTURE OF VERY THIN TIO2 FILMS STUDIED BY RAMAN-SPECTROSCOPY WITH INTERFERENCE ENHANCEMENT [J].
HUGOTLEGOFF, A .
THIN SOLID FILMS, 1986, 142 (02) :193-197
[10]  
KELLY EJ, 1974, 5TH P INT C MET CORR, P137