NEW MIXED-LIGAND ISOCYANIDE DIPHOSPHINE RUTHENIUM(II) DERIVATIVES - SYNTHESIS OF A POTENTIAL METAL-CONTAINING TETRADENTATE LIGAND

被引：7
作者：
RUIZ, J [1 ]
RIERA, V [1 ]
VIVANCO, M [1 ]
机构：
[1] UNIV OVIEDO,INST QUIM ORGANOMET,E-33071 OVIEDO,SPAIN
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 07期
关键词：
D O I：
10.1039/dt9950001069
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of trans-[RuCl2(CNPh)(4)] with an excess of Ph(2)PCH(2)PPh(2) (dppm) in refluxing toluene gave two complexes cis,cis,trans-[RUCl(2)(CNPh)(2)(dppm-P)(2)] 1 and mer- [RuCl(CNPh)(3)(dppm)]Cl 2a; whereas in the reaction of trans-[RuCl2(CNBu(t))(4)] with dppm under the same conditions only mer-[RuCl-(CNBu(t))(3)(dppm)]Cl 2b was obtained. Complex 1 reacted with TlPF6 in CH2Cl2 to give [RuCl(CNPh)(2)(dppm) (dppm-P)]PF6 3, a cationic complex containing both a monodentate and a chelated dppm ligand. Complex 1 is remarkable in having two monohapto dppm ligands and can be used in the synthesis of heterometallic species. Thus, treatment of 1 with AgClO4 or HgCl2 gave the heterometallic complex [(dppm)(PhNC)(2)ClRu(mu-dppm)AgCl]ClO4 4 or [{(dppm)(PhNC)(2)ClRu-(mu-dppm)HgCl2}(2)] Cl-2 5 respectively.
引用
收藏
页码：1069 / 1072
页数：4
相关论文
共 50 条
[21]   Synthesis and characterization of a new tetradentate ligand for Cu(II) metal ions [J].
Benshafrut, R ;
Haran, A ;
Shvarts, D ;
Schneider, B .
JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (12) :4040-4044
[22]   PHOTOPROCESSES IN MIXED-LIGAND TRIS (DIIMINE)RUTHENIUM(II) COMPLEXES [J].
VANHOUTEN, J ;
SMITH, R .
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1986, 192 :83-INOR
[23]   Conjugated polymers containing mixed-ligand ruthenium(II) complexes. Synthesis, characterization, and investigation of photoconductive properties [J].
Wang, Q ;
Yu, LP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (48) :11806-11811
[24]   EXCITED-STATES OF MIXED-LIGAND CHELATES OF RUTHENIUM(II) [J].
CROSBY, GA ;
ELFRING, WH .
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1974, :162-162
[25]   NEW MIXED-LIGAND COMPLEXES OF COBALT(II) [J].
BALUNDGI, RH ;
CHAKRAVO.A .
INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1973, 9 (10) :1045-1048
[26]   Synthesis, characterization and biological evaluation of mixed-ligand ruthenium(II) complexes for photodynamic therapy [J].
Huang, Huaiyi ;
Zhang, Pingyu ;
Yu, Bole ;
Jin, Chengzhi ;
Ji, Liangnian ;
Chao, Hui .
DALTON TRANSACTIONS, 2015, 44 (39) :17335-17345
[27]   Synthesis and Spectroscopic Properties of Mixed-Ligand Phosphine Complexes of Ruthenium(II) with Heterocyclic Thioamides [J].
Pandey, R. N. ;
Gautam, K. V. .
ASIAN JOURNAL OF CHEMISTRY, 2011, 23 (06) :2785-2787
[28]   SYNTHESIS AND CHARACTERIZATION OF MIXED-LIGAND CYCLOPENTADIENYL PYRAZOLYLBORATE COMPLEXES OF RUTHENIUM [J].
MCNAIR, AM ;
BOYD, DC ;
MANN, KR .
ORGANOMETALLICS, 1986, 5 (02) :303-310
[29]   Optimizing the synthesis of a new tetradentate mixed donor ligand [J].
Reuter, Andrew ;
Brunclik, Samuel ;
Seong, Chris ;
Marlier, Elodie .
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
[30]   The synthesis, structures and characterisation of new mixed-ligand manganese and iron complexes with tripodal, tetradentate ligands [J].
Van Gorkum, Remy ;
Berding, Joris ;
Mills, Allison M. ;
Kooijman, Huub ;
Tooke, Duncan M. ;
Spek, Anthony L. ;
Mutikainen, Ilpo ;
Turpeinen, Urho ;
Reedijk, Jan ;
Bouwman, Elisabeth .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (09) :1487-1496
12345