KINETICS OF OXIDATION OF IRON (II) TO IRON (III) IN SULFATE SOLUTION BY MANGANESE ORE

被引：0

作者：

Orlov, A. K. ^{[1
]}

机构：

[1] Tech Univ, St Petersburg State Univ, Min Inst, St Petersburg, Russia

来源：

JOURNAL OF MINING INSTITUTE | 2006年 / 169卷

关键词：

D O I：

暂无

中图分类号：

TD [矿业工程];

学科分类号：

0819 ;

摘要：

is investigated of kinetics oxidation of Fe(II) to Fe(III) by manganese ore (100-250 % from theoretical different conditions of loading) in solution, containing 2 g/dm(3) Fe(II) and 14 g/dm(3) H2SO4 at temperature 17-18 degrees C. As the result it is established that in the summary reaction 2FeSO(4) + MnO2 + 2H(2)SO(4) = Fe-2(SO4)(3) + MnSO4 + 2H(2)O, the first stage, which limits the velocity of total process, is the interaction between MnO2 and H2SO4, giving MnSO4 and atom oxygen. This oxygen than energetically oxidates FeSO4 to Fe-2(SO4)(3).

引用

页码：159 / 162

页数：4