ION SOLVATION AND ION ASSOCIATION STUDIED BY INFRARED AND MICROWAVE METHODS

被引：11
作者：
BARTHEL, J
机构：
[1] Institut für Physikalische, Theoretische Chemie der Universität Regensburg
来源：
JOURNAL OF MOLECULAR LIQUIDS | 1995年 / 65-6卷
关键词：
D O I：
10.1016/0167-7322(95)00900-7
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
FTIR spectroscopy of electrolyte solutions has been employed to distinguish among free solvent molecules, solvent molecules bound to ions, and ion aggregates themselves. Furthermore, solvation numbers and association constants have been calculated from quantitative absorption measurements. Microwave spectra confirm the information from FTIR investigations. High frequency permittivity data deduced from MW and IR measurements yield information on the dynamic processes in electrolyte solutions.
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页码：177 / 185
页数：9
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