CLASSICAL ORGANIC-REACTIONS IN PURE SUPERHEATED WATER

被引：189

作者：

KUHLMANN, B ^{[1
]}

ARNETT, EM ^{[1
]}

SISKIN, M ^{[1
]}

机构：

[1] DUKE UNIV, DEPT CHEM, DURHAM, NC 27706 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 11期

关键词：

D O I：

10.1021/jo00090a030

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

At high temperatures and pressures, pure liquid water becomes a surprisingly effective medium for the reactions of organic compounds. It may function simultaneously as a convenient solvent, catalyst, and reagent for reactions which are typically acid- or base-catalyzed. Rapid and highly selective conversions are observed for the majority of the compounds in this study.

引用

页码：3098 / 3101

页数：4

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