CLASSICAL ORGANIC-REACTIONS IN PURE SUPERHEATED WATER

被引:189
|
作者
KUHLMANN, B [1 ]
ARNETT, EM [1 ]
SISKIN, M [1 ]
机构
[1] DUKE UNIV, DEPT CHEM, DURHAM, NC 27706 USA
来源
JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 11期
关键词
D O I
10.1021/jo00090a030
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
At high temperatures and pressures, pure liquid water becomes a surprisingly effective medium for the reactions of organic compounds. It may function simultaneously as a convenient solvent, catalyst, and reagent for reactions which are typically acid- or base-catalyzed. Rapid and highly selective conversions are observed for the majority of the compounds in this study.
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页码:3098 / 3101
页数:4
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