Bis[5-chloro-2-(phenyldiazenyl-kappa N-2)pyridine-kappa N]bis(thiocyanato-kappa N)iron(II)

被引：1

作者：

Vittaya, Luksamee ^{[1
]}

Leesakul, Nararak ^{[2
,3
]}

Pakawatchai, Chaveng ^{[2
,3
]}

Saithong, Saowanit ^{[2
,3
]}

Hansongnern, Kanidtha ^{[2
,3
]}

机构：

[1] Rajamangala Univ Technol Srivijaya, Fac Sci & Fisheries Technol, Sikao 92150, Trang, Thailand

[2] Prince Songkla Univ, Fac Sci, Dept Chem, Hat Yai 90112, Songkhla, Thailand

[3] Prince Songkla Univ, Fac Sci, Ctr Innovat Chem, Hat Yai 90112, Songkhla, Thailand

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

D O I：

10.1107/S1600536812014286

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title complex, [Fe(NCS)(2)(C11H8ClN3)(2)], the Fe-II atom is coordinated by two N atoms from the thiocyanate ligands and four N atoms from two chelating 5-chloro-2-(phenyldiazenyl)-pyridine ligands, generating a fairly regular FeN6 octahedral coordination geometry. The thiocyanate ions are in a cis disposition and the pyridine N atoms are in a trans orientation. In the crystal, a short intermolecular Cl center dot center dot center dot S contact [3.366 (3) angstrom] is observed.

引用

页码：M555 / U473

页数：10

共 18 条

[1] RUTHENIUM(II) 2-(PHENYLAZO)PYRIDINE COMPLEXES AS EPOXIDATION CATALYSTS [J].