DIELECTRIC STUDY OF HYDRATION OF CYCLOHEXYLAMINE IN BENZENE

被引：9

作者：

GREGORY, MD

AFFSPRUN.HE

CHRISTIA.SD

机构：

[1] Department of Chemistry, University of Oklahoma, Norman

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1968年 / 72卷 / 05期

关键词：

D O I：

10.1021/j100851a062

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Measurements have been made of the dielectric constant of solutions of water in benzene, cyclohexylamine (CHA) in benzene, and the ternary system H2O and CHA in benzene. From the dielectric data and results of a previous distribution study of the hydration of CHA in benzene,2 dipole moments of CHA, H2O, and CHA·H2O (1.33, 1.76, and 2.82 D, respectively) were calculated. The present results support the conclusion of the previous investigation that hydrates of the amine dimer or higher polymers are not present in significant concentrations.

引用

页码：1748 / &

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[41] FREE EXCESS ENTHALPY OF BINARY-SYSTEMS OF CYCLOHEXYLAMINE AND CHLOROHEXANE WITH BENZENE, CYCLOHEXANE AND METHYLCYCLOHEXANE [J].

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STEPHAN, D .

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[42] Microwave dielectric study of water structure in the hydration process of cement paste [J].

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Yagihara, S ;

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[43] ENZYMIC HYDRATION OF BENZENE OXIDE - ASSAY AND PROPERTIES [J].

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[44] ENZYMIC HYDRATION OF BENZENE OXIDE - ASSAY AND PROPERTIES [J].

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[45] STUDY OF ION HYDRATION FROM DIELECTRIC MIXTURE FORMULA BY MICROWAVE SPECTROMETRY [J].

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[49] The dielectric constant of benzene. [J].

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[50] The dielectric constants of cyclohexane and benzene [J].

Hadamard, J .

COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES, 1937, 204 :1234-1235

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