A NEW ALPHA-HALOGLYCINE TEMPLATE FOR THE ASYMMETRIC-SYNTHESIS OF AMINO-ACID DERIVATIVES

被引：19
作者：
BADRAN, TW
EASTON, CJ
HORN, E
KOCIUBA, K
MAY, BL
SCHLIEBS, DM
TIEKINK, ERT
机构：
[1] UNIV ADELAIDE,DEPT CHEM,GPO BOX 498,ADELAIDE,SA 5001,AUSTRALIA
[2] NATL CHEM LAB,DEPT CHEM,DIV CHEM ANAL & STAND,TSUKUBA,IBARAKI 305,JAPAN
来源：
TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 02期
关键词：
D O I：
10.1016/S0957-4166(00)82336-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of (S)-N,N-diacylvalylglycine anhydride with N-bromosuccinimide afforded the corresponding alpha-bromoglycine derivative, which reacted diastereoselectively with allyltributyltin and deuterium over palladium chloride to give the corresponding alpha-allyl- and alpha-deuterio-glycine derivatives, respectively.
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页码：197 / 200
页数：4
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