Crystal structure of fbis[2-(3,5-dimethyl-pyrazol-1-yl-kappa N-2)ethyljamine-kappa N}- chloridoplatinum(II) chloride dihydrate

被引：0
|
作者：
de los Angeles Mendoza, Maria [1 ]
Bernes, Sylvain [2 ]
Mendoza-Diaz, Guillermo [1 ]
机构：
[1] Univ Guanajuato, Div Ciencias & Ingn, Dept Ingn Quim Elect & Biomed, Leon 37150, Gto, Mexico
[2] Benemerita Univ Autonoma Puebla, Inst Fis, Ave San Claudio & 18 Sur, Puebla 72570, Pue, Mexico
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词：
crystal structure; coordination compounds; bis[2-(3,5-dimethylpyrazol-1-ybethyllamine (pza) ligand; bis(pyrazol-1-amine; platinum(II) complex;
D O I：
10.1107/S2056989015005307
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title complex, [PtCl(C14H23N5)]Cl-2H(2)O, is isomorphous with the Pd" compound characterized previously [Mendoza, Bernes & Mendoza-Diaz (2006). Acta Cryst. E62, m2934 m2936]. The angle between pyrazole mean planes in the main ligand is 88.3 (4)degrees, similar to that observed in the Pe analogue [87.62 (11)degrees]. This tridentate ligand adopts a conformation approximating a twofold symmetry, allowing its coordination to the metal atom, together with a chloride ligand, in an almost perfect square -planar geometry. A chloride anion and two water molecules in the asymmetric unit form a hydrogen bonded network connected to the complex molecules in the crystal via the NH amine groups, forming chains along [100].
引用
收藏
页码：M98 / U182
页数：9
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