REAL-TIME SAMPLING ELECTRONICS FOR DOUBLE MODULATION EXPERIMENTS WITH FOURIER-TRANSFORM INFRARED SPECTROMETERS

被引:125
作者
GREEN, MJ [1 ]
BARNER, BJ [1 ]
CORN, RM [1 ]
机构
[1] UNIV WISCONSIN,DEPT CHEM,1101 UNIV AVE,MADISON,WI 53706
关键词
D O I
10.1063/1.1142462
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
A novel synchronous real-time analog sampling method for obtaining the sum and difference interferograms in double modulation Fourier transform infrared absorption experiments is described, and the application of this sampling methodology to polarization-modulation FTIR measurements of thin films at metal surfaces is demonstrated. A quadratic approximation of the background signal is used to calculate the difference interferogram. The demodulation of a test waveform with the real-time sampling electronics reveals how the bandwidth limitations of previous double modulation experiments on FTIR interferometers that employed lock-in amplifiers have been eliminated.
引用
收藏
页码:1426 / 1430
页数:5
相关论文
共 18 条
[1]   POLARIZATION MODULATION FOURIER-TRANSFORM INFRARED REFLECTANCE MEASUREMENTS OF THIN-FILMS AND MONOLAYERS AT METAL-SURFACES UTILIZING REAL-TIME SAMPLING ELECTRONICS [J].
BARNER, BJ ;
GREEN, MJ ;
SAEZ, EI ;
CORN, RM .
ANALYTICAL CHEMISTRY, 1991, 63 (01) :55-60
[2]  
BUFFETEAU T, 1988, MIKROCHIM ACTA, V2, P23, DOI 10.1007/BF01349714
[3]   FOURIER-TRANSFORM INFRARED PHOTOTHERMAL SPECTROSCOPIC CHARACTERIZATION OF PRUSSIAN BLUE SURFACE MODIFIED ELECTRODES - COUNTERCATION EFFECTS [J].
CRUMBLISS, AL ;
LUGG, PS ;
CHILDERS, JW ;
PALMER, RA .
JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (03) :482-488
[4]   A DOUBLE-MODULATION FOURIER-TRANSFORM INFRARED APPROACH TO STUDYING ADSORBATES ON METAL-SURFACES [J].
DOWREY, AE ;
MARCOTT, C .
APPLIED SPECTROSCOPY, 1982, 36 (04) :414-416
[5]   APPLICATION OF POLARIZATION-MODULATED FOURIER-TRANSFORM INFRARED REFLECTION ABSORPTION-SPECTROSCOPY TO THE STUDY OF CARBON-MONOXIDE ADSORPTION AND OXIDATION ON A SMOOTH PLATINUM-ELECTRODE [J].
GOLDEN, WG ;
KUNIMATSU, K ;
SEKI, H .
JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (07) :1275-1277
[6]   A METHOD FOR MEASURING INFRARED REFLECTION-ABSORPTION SPECTRA OF MOLECULES ADSORBED ON LOW-AREA SURFACES AT MONOLAYER AND SUBMONOLAYER CONCENTRATIONS [J].
GOLDEN, WG ;
DUNN, DS ;
OVEREND, J .
JOURNAL OF CATALYSIS, 1981, 71 (02) :395-404
[7]   FOURIER-TRANSFORM INFRARED REFLECTION-ABSORPTION SPECTROSCOPY OF SURFACE SPECIES [J].
GOLDEN, WG ;
SAPERSTEIN, DD .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1983, 30 (FEB) :43-50
[8]  
GOLDEN WG, 1984, J PHYS CHEM-US, V88, P572
[9]   REFLECTION METHOD FOR OBTAINING INFRARED SPECTRUM OF A THIN LAYER ON A METAL SURFACE [J].
GREENLER, RG .
JOURNAL OF CHEMICAL PHYSICS, 1969, 50 (05) :1963-&
[10]   INFRARED STUDY OF ADSORBED MOLECULES ON METAL SURFACES BY REFLECTION TECHNIQUES [J].
GREENLER, RG .
JOURNAL OF CHEMICAL PHYSICS, 1966, 44 (01) :310-&