THE SYNTHESIS AND CHARACTERIZATION OF RADICAL-CATION SALTS OF BIS(ETHYLENEDITHIO)TETRASELENAFULVALENE

被引：24
|
作者：
MONTGOMERY, LK
BURGIN, T
HUFFMAN, JC
CARLSON, KD
DUDEK, JD
YACONI, GA
MEGNA, LA
MOBLEY, PR
KWOK, WK
WILLIAMS, JM
SCHIRBER, JE
OVERMYER, DL
REN, J
ROVIRA, C
WHANGBO, MH
机构：
[1] ARGONNE NATL LAB,DIV CHEM,ARGONNE,IL 60439
[2] ARGONNE NATL LAB,DIV MAT SCI,ARGONNE,IL 60439
[3] SANDIA NATL LABS,ALBUQUERQUE,NM 87185
[4] N CAROLINA STATE UNIV,DEPT CHEM,RALEIGH,NC 27695
来源：
SYNTHETIC METALS | 1993年 / 56卷 / 01期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/0379-6779(93)90378-A
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Four 2:1 radical cation salts (SbF6, CF3SO3, GaCl4, Cu[N(CN)2]Br) of bis(ethylenedithio)tetraselenafulvalene (BETS) have been prepared and scrutinized by X-ray crystallography, DC resistivity measurements (300-10K), rf penetration depth experiments (0.5K), pressure studies (0.5-5kbar, 4K), and tight-binding band calculations. The salts are kappa-phase, and three are metallic to low temperatures. Kappa-(BETS)2 Cu[N(CN)2]Br is isostructural with kappa-(ET)2 Cu[N(CN)2]Br.
引用
收藏
页码：2090 / 2095
页数：6
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