SYNTHESIS, ESR AND ELECTRONIC SPECTRAL STUDIES ON COBALT(II) COMPLEXES OF SEMICARBAZONES AND THIOSEMICARBAZONES

被引：8

作者：

CHANDRA, S ^{[1
]}

GUPTA, L ^{[1
]}

TYAGI, VP ^{[1
]}

机构：

[1] MAHANAND MISS HARIJAN COLL, DEPT CHEM, GHAZIABAD, INDIA

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1995年 / 25卷 / 04期

关键词：

D O I：

10.1080/15533179508218244

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cobalt(II) complexes of the general composition, Co(L)(2)X(2) or Co(L)(2)SO4 (where L is isopropylmethylketone or isobutylmethylketone semicarbazones and thiosemicarbazones and X = Cl-, Br-, NCS-, CH3COO-) have been synthesised. All the complexes are characterised by elemental analyses, magnetic moments, IR, electronic and ESR spectral studies. The complexes were found to have magnetic moments corresponding to three unpaired electrons. The possible geometries of the complexes were assigned on the basis of electronic, infrared and ESR spectral studies.

引用

页码：537 / 550

页数：14

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