STATIC AND DYNAMIC CROSSOVER IN A CRITICAL POLYMER MIXTURE

被引:131
作者
BATES, FS
ROSEDALE, JH
STEPANEK, P
LODGE, TP
WILTZIUS, P
FREDRICKSON, GH
HJELM, RP
机构
[1] UNIV MINNESOTA,DEPT CHEM,MINNEAPOLIS,MN 55455
[2] AT&T BELL LABS,MURRAY HILL,NJ 07974
[3] UNIV CALIF SANTA BARBARA,DEPT CHEM & NUCL ENGN,SANTA BARBARA,CA 93106
[4] UNIV CALIF SANTA BARBARA,DEPT MAT,SANTA BARBARA,CA 93106
[5] UNIV CALIF LOS ALAMOS SCI LAB,DIV PHYS,LOS ALAMOS NEUTRON SCATTERING CTR,LOS ALAMOS,NM 87545
关键词
D O I
10.1103/PhysRevLett.65.1893
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
A model low-molecular-weight polymer mixture was studied as a function of temperature near the critical point by small-angle neutron scattering (SANS) and dynamic light scattering (DLS). SANS measurements reveal a crossover in the static susceptibility from mean-field to non-mean-field behavior at TxTc+30°C, in quantitative agreement with the Ginzburg criterion. This crossover behavior is also reflected in the DLS experiments, which reveal mode-coupled critical dynamics far into the mean-field regime. © 1990 The American Physical Society.
引用
收藏
页码:1893 / 1896
页数:4
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