Crystal structure of bis(thiourea-kappa S) bis(triphenyl-phosphane-kappa P) silver I) nitrate

被引：3

作者：

Nawaz, Sidra ^{[1
]}

Tahir, Muhammad Nawaz ^{[2
]}

Nadeem, Muhammad Amir ^{[1
]}

Mehmood, Bushra ^{[1
]}

Ahmad, Saeed ^{[1
]}

机构：

[1] Univ Engn & Technol, Dept Chem, Lahore 54890, Pakistan

[2] Univ Sargodha, Dept Phys, Sargodha, Punjab, Pakistan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷

关键词：

crystal structure; thiourea; triphenylphosphane; silver(I) complex; hydrogen bonding;

D O I：

10.1107/S2056989015001395

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title salt, [Ag(CH4N2S)(2)(PPh3)(2)]NO3, the Ag-I atom is coordinated by two thiourea S atoms and two triphenylphosphane P atoms in a distorted tetrahedral geometry, with bond angles in the range 102.90 (4)-123.29 (4)degrees. The Ag-S C bond angles are 101.75 (19) and 111.29 (18)degrees. In the crystal, the component ions are linked by C-H center dot center dot center dot O, C-H center dot center dot center dot S, N-H center dot center dot center dot O and N-H center dot center dot center dot S hydrogen bonds, generating (101) sheets.

引用

页码：220 / +

页数：12

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